Tuning Sodium Interfacial Chemistry with Mixed-Anion Ionic Liquid Electrolytes.

The interphase layer that forms on either the anode or the cathode is considered to be one of the critical components of a high performing battery. This solid-electrolyte interphase (SEI) layer determines the stability of the electrode in the presence of a given electrolyte as well as the internal resistance of a battery, and hence the overpotential of a cell. In the case of lithium ion batteries where carbonate based electrolytes are used, additives including hexafluorophosphate (PF), bis-trifluoromethylsulfonimide (TFSI), (fluorosulfonyl)(trifluoromethanesulfonyl)imide (FTFSI), and fluorosulfonimde (FSI) are used to obtain favorable SEI layers.