Polymer Biocompositions and Nanobiocomposites Based on P3HB with Polyurethane and Montmorillonite.

Due to the growing interest in biopolymers, biosynthesizable and biodegradable polymers currently occupy a special place. Unfortunately, the properties of native biopolymers make them not good enough for use as substitutes for conventional polymers. Therefore, attempts are being made to modify their properties.

Biobased poly(3-hydroxybutyrate acid) composites with addition of aliphatic polyurethane based on polypropylene glycols.

Poly(3-hydroxybutyrate) (P3HB) is the most important of the polyhydroxyalkanoates. It is biosynthesized, biodegradable, biocompatible, and shows no cytotoxicity and mutagenicity. P3HB is a natural metabolite in the human body and, therefore, it could replace the synthetic, hard-to-degrade polymers used in the production of implants.

Thermally stable biopolymer composites based on poly(3-hydroxybutyrate) modified with linear aliphatic polyurethanes - preparation and properties.

Purpose: Poly(3-hydroxybutyrate) (P3HB) is a biopolymer, but storing products from P3HB causes the deterioration of their properties leading to their brittleness. P3HB has also low thermal stability. Its melting point almost equals its degradation temperature.

New Mono- and Diesters with Imidazoquinolinone Ring- Synthesis, Structure Characterization, and Molecular Modeling.

The objective of the studies was to synthesize and characterize new mono- and diesters with an imidazoquinolin-2-one ring with the use of 2,3-dihydro-2-thioxo-1H-imidazo[4 ,5-c]-quinolin-4(5)-ones and ethyl bromoacetate. The products were isolated at high yield and characterized by instrumental methods (IR, H-, C-, and N- NMR, MS-ESI, HR-MS, EA). In order to clarify the places of substitution and the structure of the derivatives obtained, molecular modeling of substrates and products was performed.