Publications by authors named "Luca Chiari"

We report on the anisotropic photodetachment of positronium negative ions, followed by the dissociation into p-wave electrons and positronium atoms, with a linearly polarized laser beam. We have observed a strong recoil effect of the photoelectrons on the translation momentum of the dissociated positronium atoms. With polarization angle-resolved measurements, the asymmetry parameter of the photoemission angular distribution of the ions at a photon energy of 1.

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The imbalanced force of the interfacial tension applied to an object has often been taken into account in the analysis of the motion mechanism of self-propelled systems. However, heterogeneous distributions of the interfacial tension also cause Marangoni flows, and these flows also contribute to the self-propulsion through the viscous force. The contribution of such flows has not been observed directly, while the interfacial tension difference has been measured in some systems.

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An inclined liquid surface, such as a meniscus, plays an important role in advection and transport phenomena at a liquid's surface. However, there is no time-resolved measurement method for the interfacial tension of an inclined liquid-air interface. Here, a noninvasive method for simultaneous measurements of the interfacial tension and surface flow speed for an inclined water surface is described.

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The chemical state of the active sites in the pores of zeolites is known to greatly affect their chemical and catalytic properties, e.g. the presence of Brønsted acid sites enhances their action as polar adsorbents.

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Threshold photodetachment spectroscopy of the positronium negative ion has been accomplished for the first time employing an efficient source of the ions and photodetachment techniques combined with a tunable optical parametric oscillator and amplifier laser. The photodetachment threshold, corresponding to the electron affinity of positronium (1^{3}S_{1}), was determined to be 326.88±0.

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Although the mechanical properties and compositions of lipid bilayer membranes can change upon deformation, the fundamental relations between the composition, membrane tension and fluidity of membranes with little curvature have not yet been studied. In the current study, the membrane tension and the diffusion coefficients of free-standing black lipid membranes (BLMs), based on 1,2-dioleoyl-sn-glycero-3-phosphocholine (DOPC), were observed by systematic control of the cholesterol concentration and the osmotic pressure with the laser-induced surface deformation (LISD) and fluorescence recovery after photobleaching (FRAP) techniques. When the osmotic pressure was raised and, therefore, the curvature became larger, both the membrane tension and the diffusion coefficients increased as well.

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The self-propelled behaviors of macroscopic inanimate objects at surfaces and interfaces are ubiquitous phenomena of fundamental interest in interface science. However, given the existence of a large variety of systems with their own inherent chemical properties, the kinematics of the self-propelled motion and the dynamics of the forces driving these systems often remain largely unknown. Here, we experimentally investigate the spontaneous motion of a sodium oleate tablet at a water-nitrobenzene interface, under nonequilibrium and global isothermal conditions, through measurements of the interfacial tension with the noninvasive, quasi-elastic laser scattering method.

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Hypothesis: The existence of a surface tension difference and a surface flow around self-propelled objects, such as camphor boats, has been confirmed by many studies. However, the interactions in the collective motion of several camphor boats have not been explicitly discussed. Here, a model system of two camphor boats was investigated for the first time from the viewpoint of surface tension and surface flow.

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Utilising a high-resolution, trap-based positron beam, we have measured both elastic and inelastic scattering of positrons from water vapour. The measurements comprise differential elastic, total elastic, and total inelastic (not including positronium formation) absolute cross sections. The energy range investigated is from 1 eV to 60 eV.

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2,2,4-Trimethylpentane (C8H18), a hydrocarbon produced all over the world on a large scale in the processing of crude oil, has long been known and used in the energy sector. It has also recently attracted the attention of the radiation physics and chemistry community, owing to its applications in medical imaging techniques. Charged-particle interactions with this species unfortunately remain mostly unknown.

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Cross section results from a joint experimental and theoretical investigation into positron scattering from 3-hydroxy-tetrahydrofuran (3H-THF) are presented. Total and positronium (Ps) formation cross sections have been measured from 1 to 190 eV using the positron beamline at the Australian National University, which has an energy resolution between 60 and 100 meV. The total cross section (TCS) and the elastic and total inelastic integral cross sections in the energy range between 1 and 1000 eV have been computed within the Independent Atom Model using the Screening Corrected Additivity Rule approach.

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We present total, elastic, and inelastic cross sections for positron and electron scattering from tetrahydrofuran (THF) in the energy range between 1 and 5000 eV. Total cross sections (TCS), positronium formation cross sections, the summed inelastic integral cross sections (ICS) for electronic excitations and direct ionization, as well as elastic differential cross sections (DCS) at selected incident energies, have been measured for positron collisions with THF. The positron beam used to carry out these experiments had an energy resolution in the range 40-100 meV (full-width at half-maximum).

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