Tailoring the surface ligands of metal nanoclusters is important for engineering unique configurations of metal nanoclusters. Thiacalix[4]arene has found extensive applications in the construction of metal nanoclusters. In this investigation, we present the synthesis and characterization of the first all-calixarene-protected silver nanoclusters, [Ag(CHCN)][Ag(BTCA)] (, HBTCA = -butylthiacalix[4]arene).
View Article and Find Full Text PDFMost of polyoxometallates (POMs) templated silver nanoclusters recorded so far are polyoxomolybdates and polyoxotungstates; however, as congeneric polyoxochromates, they are rarely observed in silver nanoclusters. Herein, a high-nuclearity polyoxochromate, (CrCrO), is uncovered in a novel silver nanocluster () as an anion template. The mixed-valent (CrCrO) consists of four edge-sharing CrO octahedra and eight CrO tetrahedra, which are fused together by sharing one or two vertexes.
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