Tailoring N and S Heteroatoms Through Rational Design in Carbon Nanotubes-Graphene Composites for Enhanced Zn-Air Battery Performance.

Cathodic materials significantly influence the performance, durability, and sustainability of primary zinc-air batteries (ZABs). This study focuses on the rational design of highly active metal-free composites by tailoring the content of N and S heteroatoms in carbon nanotube-graphene (CNTG) composites. The oxygen reduction reaction (ORR) tests showed onset potentials (E) of 0.

Poly(Vinyl Alcohol)/Poly(Acrylic Acid) Gel Polymer Electrolyte Modified with Multi-Walled Carbon Nanotubes and SiO Nanospheres to Increase Rechargeability of Zn-Air Batteries.

Zn-air batteries (ZABs) are a promising technology; however, their commercialization is limited by challenges, including those occurring in the electrolyte, and thus, gel polymer electrolytes (GPEs) and hydrogels have emerged as substitutes for traditional aqueous electrolytes. In this work, PVA/PAA membranes were synthesized by the solvent casting method and soaked in 6 M KOH to act as GPEs. The thickness of the membrane was modified (50, 100, and 150 μm), and after determining the best thickness, the membrane was modified with synthesized SiO nanospheres and multi-walled carbon nanotubes (CNTs).

Green Energy Storage: Chitosan-Avocado Starch Hydrogels for a Novel Generation of Zinc Battery Electrolytes.

Meeting the ever-increasing global energy demands through sustainable and environmentally friendly means is a paramount challenge. In response to this imperative, this study is dedicated to the development of biopolymer electrolytes, which hold promise for improving the efficiency, safety, and biodegradability of energy systems. The present study aims to evaluate hydrogels synthesized from chitosan biopolymer and starch from avocado seed residues in different ratios, and dried using freeze-thawing and freeze-drying techniques.

Correction: Electrochemical creatinine detection for advanced point-of-care sensing devices: a review.

[This corrects the article DOI: 10.1039/D2RA04479J.].

Electrochemical creatinine detection for advanced point-of-care sensing devices: a review.

Creatinine is an amino acid derived from creatine catabolism at different steps of the body's organs, and its detection is significant because levels out of normal values are linked to some diseases like kidney failure. Normal concentration levels of creatinine in blood are from 45 to 110 μM, while in urine, typical concentrations range between 3.3 to 27 mM, and in saliva from 8.

Three-Dimensional-Order Macroporous ABO Spinels (A, B =Co and Mn) as Electrodes in Zn-Air Batteries.

In this work, atomically substituted three-dimensionally ordered macroporous (3DOM) spinels based on Co and Mn (MnCoO and CoMnO) were synthetized and used as cathodic electrocatalysts in a primary Zn-air battery. Scanning/transmission electron microscopy images show a 3DOM structure for both materials. Skeleton sizes of 114.

A Flow-Through Membraneless Microfluidic Zinc-Air Cell.

In this work, the proof of concept of a functional membraneless microfluidic Zn-air cell (μZAC) that operates with a flow-through arrangement is presented for the first time, where the activity and durability can be modulated by electrodepositing Zn on porous carbon electrodes. For this purpose, Zn electrodes were obtained using chronoamperometry and varying the electrodeposition times (20, 40, and 60 min), resulting in porous electrodes with Zn thicknesses of 3.3 ± 0.

Water extractable arabinoxylan aerogels prepared by supercritical CO2 drying.

Water extractable arabinoxylan (WEAX) aerogels were prepared by extracting the solvent from the alcogels (WEAX hydrogels with an alcohol as the solvent) with carbon dioxide under supercritical conditions. WEAX aerogels were characterized using scanning electron microscopy and adsorption and desorption nitrogen isotherms. The micrographs indicate a heterogeneous porous network structure in WEAX aerogel.

Arabinoxylan microspheres: structural and textural characteristics.

The aim of this research was to study the structural and textural characteristics of maize bran arabinoxylan (MBAX) microspheres. The laccase-induced cross-linking process was monitored by storage (G') and loss (G'') moduli changes in a 4% (w/v) MBAX solution. The G' and G'' values at the plateau region were 215 and 4 Pa, respectively.