Multi-Stimuli-Responsive Carbon Dots with Intrinsic Photochromism and In Situ Radical Afterglow.

The combination of advanced photoluminescence characteristics to photochromism is highly attractive in preparing high-performance multifunctional photo-responsive materials for optoelectronic applications. However, this is rather challenging in material design owing to the limited mechanism understanding and construction principles. Here, an effective strategy to integrate photochromism and afterglow emission in carbon dots (CDs) is proposed through embedding naphthaleneimide (NI) structure in CDs followed by polyvinylpyrrolidone (PVP) encapsulation.

Hybrid Local and Charge-Transfer Material with Ultralong Room Temperature Phosphorescence for Efficient Organic Afterglow Light-Emitting Diodes.

Organic ultralong room temperature phosphorescence (OURTP) materials capable of combining various emission behaviors for diversified optoelectronic properties and applications have recently gained a vigorous development, but it remains a forbidden challenge in designing OURTP molecules with hybrid local and charge-transfer (HLCT) feature, possibly due to the elevated difficulties in simultaneously meeting the stringent requirements of both HLCT and OURTP emitters. Here, through introducing multiple heteroatoms into one-dimensional fused ring of coumarin with moderate charge transfer perturbation in donor-π-acceptor architecture, we demonstrate a HLCT-featured OURTP molecule showing both promoted fluorescence with a quantum yield of 77 % in solution and long-lived OURTP with a lifetime of 251 ms in conventional host material used in electroluminescent device. Thus, efficient OURTP organic light-emitting diodes (OLEDs) were fabricated, exhibiting bright electroluminescence with an exciton utilization efficiency of 85 % and yellow OURTP lasting over 2 s for afterglow.

Stimulating Phonon Bottleneck Effect in Organic Semiconductors by Charge-Transfer-Mediated J-Aggregation.

Hot carriers rapidly lose kinetic energies on a subpicosecond time scale, posing significant limitations on semiconductors' photon-conversion efficiencies. To slow the hot carrier cooling, the phonon bottleneck effect is constructed prevalently in quantum-confined structures with discrete energy levels. However, the maximum energy separation (Δ) between the energy levels is in a range of several hundred meV, leading to unsatisfactory cooling time.

High-Quality Circularly Polarized Organic Afterglow from Nonconjugated Amorphous Chiral Copolymers.

Organic materials featuring circularly polarized luminescence (CPL) and/or afterglow emission represent an active research frontier with promising applications in various fields, but the achievement of high-performance CPL organic afterglow (CPOA) remains a huge challenge due to the intrinsic contradictions between the luminescent lifetime/dissymmetry factor () and phosphorescent quantum efficiency (PhQY). Herein, we report a simple and universal approach to design efficient CPOA from amorphous copolymers by incorporating chiral chromophores into a nonconjugated clusterization-triggered emissive polymer with plenty of hydron-bonding interactions, followed by aggregation engineering using water dissolution and evaporation. With this chiral copolymerization and aggregation engineering (CCAE) strategy, high-performance CPOA polymers with PhQYs of up to 6.

Highly Efficient and Robust Full-Color Organic Afterglow through 2D Superlattices Embedment.

Purely organic afterglow (POA) originating from the slow radiative decay of stabilized triplet excited states has shown amazing potential in many fields. However, achieving highly stable POA with high phosphorescent quantum yield (PhQY) and long lifetime is still a formidable challenge owing to the intrinsically active and sensitive nature of triplet excitons. Here, triplet excitons of phosphors are protected and stabilized by embedding in tricomponent trihapto self-assembled 2D hydrogen-bonded superlattices, which not only enables deep-blue POA with high PhQY (up to 65%), ultralong lifetime (over 1300 ms) and the highest figure-of-merit at room temperature, but also achieves excellent stability capable of resisting quenching effects of oxygen, solvent, pressure, light, and heat.

On-demand modulating afterglow color of water-soluble polymers through phosphorescence FRET for multicolor security printing.

Developing full-color organic ultralong room temperature phosphorescence (OURTP) materials with continuously variable afterglow emission is of considerable practical importance in diverse optoelectronic applications but remains a formidable challenge. Here, we present an effective strategy for on-demand engineering of afterglow color in water-soluble polymeric systems via efficient phosphorescence Förster resonance energy transfer. Using a blue afterglow emitting water-soluble polymer as host and a series of fluorescent emitters with varied emissive colors as guests, afterglow emission is rationally modulated, conferring the full-color afterglow emission ranging from blue to red and even white with ultralong lifetimes up to 4.

Research Advances in Hierarchically Structured PVDF-Based All-Organic Composites for High-Energy Density Capacitors.

Polymer film capacitors have been widely applied in many pulsed power fields owing to their fastest energy-released rates. The development of ferroelectric polyvinylidene fluoride (PVDF)-based composites has become one of the hot research directions in the field of high-energy storage capacitors. Recently, hierarchically-structured all-organic composites have been shown to possess excellent comprehensive energy storage performance and great potential for application.

Overexpression of a Cotton Aquaporin Gene Confers Cold Tolerance in Transgenic .

Cold stress can significantly affect the development, yield, and quality of crops and restrict the geographical distribution and growing seasons of plants. Aquaporins are the main channels for water transport in plant cells. Abiotic stresses such as cold and drought dehydrate cells by changing the water potential.

Modulating Tri-Mode Emission for Single-Component White Organic Afterglow.

Achieving single-component white organic afterglow remains a great challenge owing to the difficulties in simultaneously supporting long-lived emissions from varied excited states of a molecule for complementary afterglow. Here, an extraordinary tri-mode emission from the radiative decays of singlet (S ), triplet (T ), and stabilized triplet (T ) excited states was proposed to afford white afterglow through modulating the singlet-triplet splitting energy (ΔE ) and exciton trapping depth (E ). Low-lying T * for yellow afterglow was constructed by H-aggregation engineering with large E and trace isomer doping, while high-lying T and S for blue afterglow with thermally activated emission feature were realized by reducing ΔE through donor-acceptor molecular design.

Stimuli-Responsive Deep-Blue Organic Ultralong Phosphorescence with Lifetime over 5 s for Reversible Water-Jet Anti-Counterfeiting Printing.

Organic ultralong room temperature phosphorescence (OURTP) materials with photophysical properties sensitive to external stimulus are highly attractive for advanced applications. However, most OURTP molecules are in crystal and OURTP materials with good practicability and stimulus-responsive character are hard to be achieved. Here, we report, for the first time, the highly efficient, ultralong-lived and deep-blue OURTP materials by simply doping boron phosphor into cyanuric acid host.

Transcriptome Analysis Reveals a Gene Expression Pattern Associated with Fuzz Fiber Initiation Induced by High Temperature in .

is an important source of natural textile fibers, as is . Cotton fiber development is often affected by various environmental factors, such as abnormal temperature. However, little is known about the underlying mechanisms of temperature regulating the fuzz fiber initiation.

Transcriptomic Profiling of Young Cotyledons Response to Chilling Stress in Two Contrasting Cotton ( L.) Genotypes at the Seedling Stage.

Young cotyledons of cotton seedlings are most susceptible to chilling stress. To gain insight into the potential mechanism of cold tolerance of young cotton cotyledons, we conducted physiological and comparative transcriptome analysis of two varieties with contrasting phenotypes. The evaluation of chilling injury of young cotyledons among 74 cotton varieties revealed that H559 was the most tolerant and YM21 was the most sensitive.

Adaptability of the structure and biomass of Arundinaria spanostachya clonal populations grazing by wild giant pandas.

To understand the defense mechanism of Arundinaria spanostachya clonal populations in response to grazing by giant pandas, dynamic variations in A. spanostachya clonal population structure and biomass allocation in a wild giant panda habitat at the Liziping Nature Reserve were evaluated, as well as whether the clonal populations would be continuously used by the wild giant pandas. The population density of each age-class in the grazed and control plots after grazing (2014a and 2015a) was similar to that before grazing (2013a).

A cross-sectional serum investigation of a clustering hepatitis C virus infection in Southwest China.

Serum samples were collected in a village with a clustering hepatitis C virus (HCV) infection. HCV antibody, HCV RNA loads, liver function indexes, HCV envelope antibody, and neutralizing activity were assessed. Among 851 adult sera, 342 samples were positive for anti-HCV.

Reduction of selenite to red elemental selenium by Rhodopseudomonas palustris strain N.

The trace metal selenium is in demand for health supplements to human and animal nutrition. We studied the reduction of selenite (SeO₃⁻²) to red elemental selenium by Rhodopseudomonas palustris strain N. This strain was cultured in a medium containing SeO₃⁻² and the particles obtained from cultures were analyzed using transmission electron microscopy (TEM), energy dispersive microanalysis (EDX) and X ray diffraction analysis (XRD).