Enhancing the Thermoelectric Properties of Conjugated Polymers by Suppressing Dopant-Induced Disorder.

Doping is a crucial strategy to enhance the performance of various organic electronic devices. However, in many cases, the random distribution of dopants in conjugated polymers leads to the disruption of the polymer microstructure, severely constraining the achievable performance of electronic devices. Here, it is shown that by ion-exchange doping polythiophene-based P[(3HT)-stat-(T)] (x = 0 (P1), 0.

Ionic transport in nematic liquid crystals and alignment layer effects on electrode polarization.

The physical properties of a liquid crystal-ionic liquid system were investigated. Low-frequency dielectric spectroscopy for 4-cyano-4'-pentylbiphenyl () doped with 1-butyl-3-methylimidazolium tetrafluoroborate ( ) for the nematic and isotropic phase of host substances was performed. We obtained electrical conductivity values in the range from 298.

Maxwell-Wagner-Sillars effects on the thermal-transport properties of polymer-dispersed liquid crystals.

We present the depolarization field effects (Maxwell-Wagner-Sillars effect) for the thermal transport properties of polymer dispersed liquid crystal composites under a frequency-dependent electric field. The experiments were conducted on polystyrene/4-Cyano-4'-pentylbiphenyl (PS/5CB) PDLCs of 73 vol.% and 85 vol.

Electrical conductivity and glass formation in nitrile-functionalized pyrrolidinium bis(trifluoromethylsulfonyl)imide ionic liquids: chain length and odd-even effects of the alkyl spacer between the pyrrolidinium ring and the nitrile group.

The electrical conductivity of a series of pyrrolidinium bis(trifluoromethylsulfonyl)imide ionic liquids, functionalized with a nitrile (cyano) group at the end of an alkyl chain attached to the cation, was studied in the temperature range between 173 K and 393 K. The glass formation of the ionic liquids is influenced by the length of the alkyl spacer separating the nitrile function from the pyrrolidinium ring. The electrical conductivity and the viscosity do not show a monotonic dependence on the alkyl spacer length, but rather an odd-even effect.

Depth estimation of surface cracks on metallic components by means of lock-in thermography.

In this work, a new method to characterize vertical cracks by lock-in thermography is presented. The heat transfer process induced by a modulated thermal excitation located in the vicinity of the crack is simulated using a finite element method computer package. The propagation of heat flow along the solid surface is disturbed when crossing an inhomogeneity.

Fragility of supercooled liquids from differential scanning calorimetry traces: theory and experiment.

Starting from the Debye model for frequency-dependent specific heat and the Vogel-Fulcher-Tammann (VFT) model for its relaxation time, an analytic expression is presented for the heat capacity versus temperature trace for differential scanning calorimetry (DSC) of glass transitions, suggesting a novel definition of the glass transition temperature based on a dimensionless criterion. An explicit expression is presented for the transition temperature as a function of the VFT parameters and the cooling rate, and for the slope as a function of fragility. Also a generalization of the results to non-VFT and non-Debye relaxation is given.

Influence of the anion on the electrical conductivity and glass formation of 1-butyl-3-methylimidazolium ionic liquids.

Six ionic liquids based on the 1-butyl-3-methylimidazolium cation have been studied. As anions Cl(-), Br(-), I(-), [NCS](-), [N(CN)(2)](-), and [BF(4)](-) were selected. The electrical conductivities were determined between 173 and 393 K based on impedance measurements in the frequency range from 0.

Temperature dependence of the electrical conductivity of imidazolium ionic liquids.

The electrical conductivities of 1-alkyl-3-methylimidazolium tetrafluoroborate ionic liquids and of 1-hexyl-3-methylimidazolium ionic liquids with different anions were determined in the temperature range between 123 and 393 K on the basis of dielectric measurements in the frequency range from 1 to 10(7) Hz. Most of the ionic liquids form a glass and the conductivity values obey the Vogel-Fulcher-Tammann equation. The glass transition temperatures are increasing with increasing length of the alkyl chain.

On the accurate determination of thermal diffusivity of liquids by using the photopyroelectric thickness scanning method.

An enhanced accurate method of measuring the thermal diffusivity of liquids by the sample's thickness scan of the phase of the photopyroelectric signal is presented. The method, making use of the absolute values of the phase and sample thickness, leads to very accurate results for the room temperature values of thermal diffusivity (about +/-0.3%).