Visible-Light-Triggered Radical-Addition/Ring-Opening Cascade Reactions of 2-Indazoles to Access -Alkoxycarbonylated Azobenzenes.

A series of asymmetric azobenzenes have been synthesized by radical-addition/ring-opening cascade reactions from 2-indazole in the presence of PIFA and alcohols under blue light irradiation and nitrogen protection. Furthermore, a wide range of functional groups were tolerated and the corresponding products were obtained in 30% to 95% isolated yields. The protocol is characterized by its visible-light initiation, avoidance of metals and photocatalysts, mild reaction conditions, and may find potential use in materials science and medicinal chemistry.

Photochemical acridone-mediated direct arylation of (hetero)arenes with aryl diazonium salts.

A metal-free photochemical C-H direct arylation using acridone as a photoredox catalyst to facilitate the reaction is described. Diazonium salts as precursors for aryl radicals, demonstrated by a fluorescence quenching experiment and free radical trapping experiment, allow the functionalization of (hetero)arenes under mild conditions. A series of valuable substituted biaryl and aryl-heteroaryl compounds were prepared in moderate to good yields the coupling.

Integrated green mining technology of "coal mining-gangue washing-backfilling-strata control-system monitoring"-taking Tangshan Mine as a case study.

In Tangshan Mine, there are four engineering problems, including the layout of multiple seam mining system, serious environmental damages caused by gangue accumulation and surface collapse, nearly 100 million tons of three under coal (coal trapped under buildings, water bodies, and railways) to be released, and the control accuracy of stratum formations to be improved. The work developed the integrated green mining technology of coal mining, gangue washing-backfilling, strata control, and system monitoring. First, a production system was designed for surface-underground transportation of backfilling materials, underground gangue separation, multiple-seam combined backfilling, and mining.