In this study, levan from Bacillus licheniformis NS032 was modified in an aqueous medium by octenyl succinic anhydride (OSA), and the properties of the obtained derivatives were studied. The maximum efficiency in the synthesis reaction was achieved at 40 °C and a polysaccharide slurry concentration of 30 %. Increasing the reagent concentration (2-10 %) led to an increase in the degree of substitution (0.
View Article and Find Full Text PDFThe increased commercial use and spread of nanoceria raises concerns about the risks associated with its effects on living organisms. Although may be ubiquitous in nature, it is largely found in locations closely linked with human activity. san ai was used as a model organism for a deeper understanding of the interaction between biomolecules of the bacteria with this intriguing nanomaterial.
View Article and Find Full Text PDFNovel Zn-Co-CeO protective composite coatings were deposited successfully from chloride plating solutions. Two different types of ceria sources were used and compared: commercial ceria powder and home-made ceria sol. Electrodeposition was performed by a direct current in the range of 1-8 A dm.
View Article and Find Full Text PDFCerium dioxide (CeO) finds applications in areas such as corrosion protection, solar cells, or catalysis, finding increasing applications in biomedicine. This work reports on surface-modified CeO particles in order to tune their applicability in the biomedical field. Stable aqueous CeO sol, consisting of 3-4 nm in size crystallites, was synthesized using forced hydrolysis.
View Article and Find Full Text PDFJ Environ Sci Health A Tox Hazard Subst Environ Eng
September 2019
The sorption ability of biogenic hydroxyapatite (BHAP) towards heavy metal ions (Pb, Cu, Ni, Cd, and Zn) is compared with functionalized BHAP powders with caffeic acid (CA) and 3,4-dihydroxybenzoic acid (3,4-DHBA). The functionalization of the BHAP with either CA or 3,4-DHBA is indicated by the appearance of the colored powders due to the formation of the interfacial charge transfer (ICT) complexes. The detailed characterization of as-prepared and functionalized BHAP samples was performed using transmission electron microscopy, reflection spectroscopy, thermogravimetric analysis and determination of zeta potential.
View Article and Find Full Text PDFJ Environ Sci Health A Tox Hazard Subst Environ Eng
July 2016
The prospects of rinsed red mud (alumina production residue) utilization for liquid radioactive waste treatment have been investigated, with Co(2+) and Sr(2+) as model cations of radioactive elements. To evaluate the sorption effectiveness and corresponding binding mechanisms, the process was analyzed in batch conditions, by varying experimental conditions (pH, Co(2+) and Sr(2+) concentrations in single solutions and binary mixtures, contact time, and the concentration of competing cations and ligands common in liquid radioactive waste). Comparison of the Co(2+) and Sr(2+) sorption pH edges with the red mud isoelectric point has revealed that Co(2+) removal took place at both positive and negative red mud surface, while Sr(2+) sorption abruptly increased when the surface became negatively charged.
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