With the increasing sales of electric vehicles, lots of spent lithium-ion batteries (LIBs) assembled with LiFePO (LFP) cathodes will retire in the next few years, posing a significant challenge for their effective and environmentally-friendly recycling. The main reason why spent LFP cathodes fail to re-utilize lies in the lattice defects caused by lithium loss and structural defects resulting from stress accumulation. In this work, we propose an in situ granule reconstruction strategy to directly regenerate spent LFP black mass (S-BM) using glycerol in industry settings.
View Article and Find Full Text PDFFatal polysulfide shuttling, sluggish sulfur redox kinetics and detrimental lithium dendrites have curtailed the real discharge capacity, working lifespan and safety of lithium-sulfur (Li-S) batteries. Organic small molecule promotors as one type of emerging active catalysts can fulfil the management of the electrochemical species evolution behaviors. Herein, an integrated engineering is organized by synthesizing dual chlorine-bridge enabled binuclear copper complex (Cu(phen)Cl) and its derivative generated in electrolyte (Cu-ETL) as the heterogeneous and homogeneous catalyst, respectively.
View Article and Find Full Text PDFThe kinetically retarded sulfur evolution reactions and notorious lithium dendrites as the major obstacles hamper the practical implementation of lithium-sulfur batteries (LSBs). Dual metal atom catalysts as a new model are expected to show higher activity by their rational coupling. Herein, the dual-atom catalyst with coupled Ni─Co atom pairs (Ni/Co-DAC) is designed successfully by programmed approaches.
View Article and Find Full Text PDFVO affords ultrafast polysulfide adsorption on account of its oxidation potential, which matches the sulfur working window (1.7-2.8 V).
View Article and Find Full Text PDFLithium-sulfur (Li-S) batteries suffer from severe polysulfide shuttle, retarded sulfur conversion kinetics and notorious lithium dendrites, which has curtailed the discharge capacity, cycling lifespan and safety. Engineered catalysts act as a feasible strategy to synchronously manipulate the evolution behaviors of sulfur and lithium species. Herein, a chlorine bridge-enabled binuclear copper complex (Cu-2-T) is in situ synthesized in electrolyte as homogeneous catalyst for rationalizing the Li-S redox reactions.
View Article and Find Full Text PDFEngineering atom-scale sites are crucial to the mitigation of polysulfide shuttle, promotion of sulfur redox, and regulation of lithium deposition in lithium-sulfur batteries. Herein, a homonuclear copper dual-atom catalyst with a proximal distance of 3.5 Å is developed for lithium-sulfur batteries, wherein two adjacent copper atoms are linked by a pair of symmetrical chlorine bridge bonds.
View Article and Find Full Text PDFLithium-sulfur (Li-S) batteries are considered as one of the most promising candidates to achieve an energy density of 500 Wh kg⁻ . However, the challenges of shuttle effect, sluggish sulfur conversion kinetics, and lithium-dendrite growth severely obstruct their practical implementation. Herein, multiscale V C MXene (VC) with a spherical confinement structure is designed as a high-efficiency bifunctional promotor for the evolution of sulfur and lithium species in Li-S batteries.
View Article and Find Full Text PDFAdv Sci (Weinh)
November 2022
The viability of lithium-sulfur (Li-S) batteries toward real implementation directly correlates with unlocking lithium polysulfide (LiPS) evolution reactions. Along this line, designing promotors with the function of synchronously relieving LiPS shuttle and promoting sulfur conversion is critical. Herein, the nitrogen evolution on hierarchical and atomistic Ni-N-C electrocatalyst, mainly pertaining to the essential subtraction, reservation and coordination of nitrogen atoms, is manipulated to attain favorable Li-S pouch cell performances.
View Article and Find Full Text PDFVC/phosphorus defect-integrated carbon (VPC) is proposed as a dual-function promoter for Li-S chemistry. The well-dispersed VC and phosphorus defects exhibit ample polar sites and remarkable electron conductivity. Such rational integration of dual active centers simultaneously suppresses the shuttle effect and propels the Li-S redox reaction kinetics.
View Article and Find Full Text PDFPorous carbon and metal oxides/sulfides prepared by using metal-organic frameworks (MOFs) as the precursors have been widely applied to the realm of supercapacitors. However, employing MOF-derived metal phosphides as positive and negative electrode materials for supercapacitors has scarcely been reported thus far. Herein, two types of MOFs are used as the precursors to prepare CoP and FeP nanocubes through a two-step controllable heat treatment process.
View Article and Find Full Text PDFThe hierarchical structural evolution of natural rubber (NR) filled with different contents of nanoscale carbon black (CB) (10 phr-CB10 and 50 phr-CB50) after first loading and recovering for different times was investigated by X-ray nano-CT, wide-angle X-ray scattering (WAXS) and solid state NMR techniques. The CB filler structures as captured by X-ray nano-CT recover gradually with increasing recovering time, but the filler network with different CB contents shows dramatically different structure evolution. For CB10, limited by the filling content, CB particles mainly induces a hydrodynamic effect in spite of deformation or recovering.
View Article and Find Full Text PDFHigh-efficient nanosheets exfoliation and ordered controlled stacking are in urgent need of work for electrochemistry application. Here, we have developed a high-efficient and environmentally-friendly solid-phase method for the exfoliation of Co-Al layered double hydroxide (Co-Al LDH) and graphene oxide (GO). Meanwhile, we found that there is a dynamic structure evolution in the self-assembly process between Co-Al LDH-NS and GO-NS and new theoretical structure models were proposed.
View Article and Find Full Text PDFLayered double hydroxides (LDHs), as an effective oxygen evolution reaction (OER) electrocatalyst, face many challenges in practical applications. The main obstacle is that bulk materials limit the exposure of active sites. At the same time, the poor conductivity of LDHs is also an important factor.
View Article and Find Full Text PDFIn this work thermo sensitivity was investigated with the bound rubber theory and thermoelasticity theory of the polymer-filler interface interaction between Polymethylvinylsiloxane (PMVS) and nanofillers (fumed and precipitated silica with the primary particle size of 10 nanometres). Bound rubber (the transition phase between PMVS and silica) content was measured by sol-gel analysis and swelling experiments. Results showed that the amount of bound rubber increases steadily with the increases of filler content.
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