The van der Waals thiophosphate GaPS presents additional opportunities for gallium-based semiconductors, but limited research on phonon interactions has hindered optimization on thermal properties. This research undertakes a comprehensive investigation into the anharmonic phonon scattering within GaPS. The findings reveal pronounced anharmonic scattering, with both cubic and quartic phonon scatterings significantly influencing phonon redshift and broadening.
View Article and Find Full Text PDFMaterials (Basel)
November 2024
The nitrogen bubble bursting phenomenon during the welding process of high nitrogen steel (HNS) can lead to unstable droplet transfer and welding process, reducing the quality of weld formation. In this study, a novel approach, ultrasonic-assisted gas metal arc welding (U-GMAW), is proposed to suppress the escape of nitrogen gas during droplet transfer. This study investigates the influence of ultrasound on the metal transfer process during two distinct metal transfer modes: short-circuiting and droplet transfer.
View Article and Find Full Text PDFCurrently, research on Ag nanoparticles (AgNPs) predominantly focuses on UV/visible photodetection and UV emission, seemingly overlooking the significance of Ag in enhancing deep ultraviolet photon detection. In this work, (InGa)O thin films were fabricated by plasma-enhanced chemical vapor deposition. Due to the unique photoabsorbance characteristic and better interaction with photons of small-sized AgNPs, they effectively suppress the UVB absorbance caused by energy band engineering in the (InGa)O thin film while enhancing photoabsorbance in UVC due to the surface plasmon effect.
View Article and Find Full Text PDFAs classical soft materials, conductive hydrogels have attracted wide attention in the field of strain sensors due to their unique flexibility and conductivity. However, there are still challenges in developing conductive hydrogels with comprehensive mechanical strength, self-healing ability and sensitive sensing properties. In this paper, a novel PAV/CMGG hydrogel was prepared by a simple one-pot method through the introduction of 1-vinyl-3-butylimidazolium bromide (VBIMBr), acrylic acid (AA), carboxymethyl guar gum (CMGG) and AlCl.
View Article and Find Full Text PDFNifedipine (NIF) is a dihydropyridine calcium channel blocker primarily used to treat conditions such as hypertension and angina. However, its low solubility and low bioavailability limit its effectiveness in clinical practice. Here, we developed a cocrystal prediction model based on Graph Neural Networks (CocrystalGNN) for the screening of cocrystals with NIF.
View Article and Find Full Text PDFRising wide bandgap semiconductor gallium oxide (GaO) displays huge potential in performing solar-blind photodetection, with constraint in narrow detection wavebands in nature, whereas bandgap modulation through the introduction of exotic atoms into GaO has an essential effect on the tunable performance of photodetectors and the detection waveband. Here, a novel method for the preparation of (InGa)O alloy films is proposed, and the continuous tuning of the bandgap in the range of 3.70-4.
View Article and Find Full Text PDFIn this work, a solar-blind UV metal-semiconductor Schottky photodiode array is constructed by using metalorganic chemical vapor deposition grown ε-GaO thin film, possessing high-performance and self-powered characteristics, toward dual-mode (self-powered and biased modes) binary light communication. For the array unit, the responsivity, specific detectivity, and external quantum efficiency are 30.8 A/W/6.
View Article and Find Full Text PDFAs an ultra-wide bandgap semiconductor, gallium oxide (GaO) has been extensively applied in solar-blind photodetectors (PDs) owing to the absorbance cut-off wavelength of shorter than 280 nm, and the optimized technologies of detection performance is seriously essential for its further usages. Herein, a feasible thermal reorder engineering method was performed through annealing GaOfilms in vacuum, Oand oxygen plasma atmospheres, realizing to tune solar-blind photosensing performance of GaOPDs. Thermal treatment, in fact a crystal reorder process, significantly suppressed the noise in GaO-based PDs and enhanced the photo-sensitivity, with the dark current decreasing from 154.
View Article and Find Full Text PDFThis research focuses on the evolution of mechanical behavior of bimodal mixtures undergoing compaction and diametrical compression. The clusters were built and discrete element method (DEM) was used to investigate the densification process and micromechanics of bimodal mixtures. Additionally, a more comprehensive investigate of the respective breakage of the bimodal mixtures has been carried out.
View Article and Find Full Text PDFTo realize on stable and real-time monitoring of human activities, novel hydrogels using polyacrylic acid (PAA) and carboxymethyl guar gum (CMGG) were fabricated as wearable and flexible strain or pressure sensors in the presence of lignosulfonate (LS) and Al. Based on the co-existence of metal coordination bonds, hydrogen bonds and ionic interaction in this system, the obtained hydrogels exhibited desirable mechanical properties with good self-recovery ability. The hydrogels displayed good self-adhesion behavior and an ultra-high tensile sensitivity (gauge factor (GF) = 24.
View Article and Find Full Text PDFNanotechnology
November 2023
With the continuous advancement of deep-ultraviolet (DUV) communication and optoelectronic detection, research in this field has become a significant focal point in the scientific community. For more accurate information collection and transport, the photodetector array of many pixels is the key of the UV imaging and commnication systems, and its photoelectric performance seriously depends on semiconductor material and array layout. Gallium oxide (GaO) is an emerging wide bandgap semicondutor material which has been widely used in DUV dectection.
View Article and Find Full Text PDFThe research and development trend of food packaging is changing from synthetic polymers to eco-friendly materials such as polysaccharides and other hydrocolloids, aiming to solve the problem of pollution from plastic wastes. In this work, a biodegradable food packaging noted KC/PT film was constructed using konjac glucomannan (KGM)/carrageenan (CAR) composite as the matrix and peppermint essential oil (PO)/thymol (THY) with synergistic effect as the reinforcements. The KC/PT film showed great mechanical properties, UV-blocking activity, increased water contact angle and reduced water vapor permeability.
View Article and Find Full Text PDFACS Appl Mater Interfaces
August 2023
Solar-blind UV photodetectors have outstanding reliability and sensitivity in flame detection without interference from other signals and response quickly. Herein, we fabricated a solar-blind UV photodetector based on a LaO/ε-GaO p-n heterojunction with a typical type-II band alignment. Benefiting from the photovoltaic effect formed by the space charge region across the junction interface, the photodetector exhibited a self-powered photocurrent of 1.
View Article and Find Full Text PDFAn edible food packaging gelatin/zein nanofiber film co-loaded with cinnamaldehyde (CA)/thymol (THY) was developed, which possessed outstanding features conducive to strawberries preservation. Firstly, the synergistic antibacterial behavior of CA and THY was investigated. Then CA and THY were co-loaded into gelatin/zein nanofiber films by electrospinning technology.
View Article and Find Full Text PDFNanomaterials (Basel)
April 2023
In this study, magnetic graphene oxide (MGO) nanohybrids were first prepared by loading FeO NPs onto graphene oxide (GO). Then, GS-MGO nanohybrids were prepared by grafting gentamicin sulfate (GS) onto MGO directly using a simple amidation reaction. The prepared GS-MGO had the same magnetism as MGO.
View Article and Find Full Text PDFIn high shear wet granulation (HSWG), the interaction mechanism between binder and powder with different sugar content is still unclear. Herein, the law and mechanism of the interaction between binder and powder were studied on the molecular level by combining experiment analysis through the Kriging model and molecular dynamics (MD) simulation. For the sticky powder with high sugar content, the ethanol in the binder played a pivotal role in dispersing water into powders, and the amount of water determined the growth of granules.
View Article and Find Full Text PDFThe potato's most devastating disease is late blight, which is caused by Phytophthora infestans. Whereas various resistance (R) genes are known, most are typically defeated by this fast-evolving oomycete pathogen. However, the broad-spectrum and durable R8 is a vital gene resource for potato resistance breeding.
View Article and Find Full Text PDFIntroduction: Allogeneic hematopoietic stem cell transplantation (allo-HSCT) is the standard and curative treatment strategy for patients with hematologic malignancies. Recently, decitabine-included regimens have been investigated by several studies including ours, which may prevent relapse of primary malignant diseases.
Methods: This study was to retrospectively evaluate a 7-day decitabine-included regimen with reduced dose of idarubicin for patients with hematologic malignancies who underwent allo-HSCT.
To provide a theoretical foundation and a good understanding for the real manufacturing granulation process, this paper investigates the effect of particle properties on the mixing process in the high-shear wet granulator, a common equipment in one of the key technologies in the growth of the pharmaceutical industry that has rarely been used to examine particle mixing-related problems in previous numerical simulations. The discrete element method (DEM) and the relative standard deviation (RSD) to explore binary particle systems with a range of sizes, densities, and volume fractions, and measure the mixing homogeneity of the particles. Results show that, for binary particle systems, particle size, density, and volume fraction all significantly affect mixing homogeneity, with good mixing occurring for a single size and a 1:1 volume fraction for the same density.
View Article and Find Full Text PDFAs a typical broad bandgap semiconductor, ZnO has received considerable attention for developing optoelectronic devices in ultraviolet wavelengths, but suffers from a lack of high-quality single-crystalline p-type ZnO. Herein, we report the realization of a homojunction ultraviolet photodetector, which involves a p-type Sb-doped ZnO microwire (ZnO:Sb MW) and n-type ZnO layer. The p-type conductivity of the as-synthesized ZnO:Sb MWs was evidenced using an individual wire field-effect transistor.
View Article and Find Full Text PDFPotato is the most important non-grain food in the world, while late blight caused by seriously threatens the production of potato. Since pathogen-associated molecular patterns (PAMPs) are relatively conserved, PAMP-triggered immunity (PTI) can provide durable resistance to late blight for potato. However, knowledge of the regulatory mechanisms of PTI against oomycete pathogens at protein levels remains limited due to the small number of identified proteins.
View Article and Find Full Text PDFLack of highly efficient, inexpensive, and easily available catalysts severely limits the practical applicability of electrochemically sensing assay towards 5-hydroxytryptamine (5-HT). Herein, four kinds of Fe-Co bimetallic Prussian blue analogues (FeCo-PBAs) with different molar ratios of Fe to Co were prepared using a simple coprecipitation method. Interestingly, Fe(III) in K [Fe(CN)] can be reduced to Fe(II) by adding trisodium citrate dehydrate, which could offer a new clue to synthesize PBAs with Fe(II) core ions.
View Article and Find Full Text PDFL. () is a vital oilseed crop cultivated worldwide; low temperature (LT) is one of the major stress factors that limit its growth, development, distribution, and production. Even though processes have been developed to characterize LT-responsive genes, only limited studies have exploited the molecular response mechanisms in .
View Article and Find Full Text PDFRapeseed ( L.) is an important oilseed crop globally. However, its growth and production are significantly influenced by cold stress.
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