Integrating the hydrogen evolution reaction (HER) and urea oxidation reaction (UOR) is an energy-saving approach for electrolytic H production. Here, hollow NiCoP nanoprisms are derived from Prussian blue analogues by a combined self-template coordination reaction and gas-phase phosphorization strategy. Benefiting from the strong electron interaction, unique hollow nanostructure, and enhanced mass/charge transfer, NiCoP nanoprisms display outstanding alkaline HER and UOR performance.
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