Nanoscale Mapping and Spectroscopy of Nonradiative Hyperbolic Modes in Hexagonal Boron Nitride Nanostructures.

The inherent crystal anisotropy of hexagonal boron nitride (hBN) provides the ability to support hyperbolic phonon polaritons, that is, polaritons that can propagate with very large wave vectors within the material volume, thereby enabling optical confinement to exceedingly small dimensions. Indeed, previous research has shown that nanometer-scale truncated nanocone hBN cavities, with deep subdiffractional dimensions, support three-dimensionally confined optical modes in the mid-infrared. Because of optical selection rules, only a few of the many theoretically predicted modes have been observed experimentally via far-field reflection and scattering-type scanning near-field optical microscopy (s-SNOM).

Help or Hindrance? The Support Person in the Psychiatric Medico-legal Examination.

The option of having a support person available in industrial disputes and disciplinary hearings has become a well-accepted practice. However, the implications of having a third party present and the potential for inhibition of disclosure in the forensic psychiatric/psychological assessment has not been examined in more than a limited fashion. Expectations of claimants and lawyers that the presence of a support person is a right and assumptions that altering the usual one-to-one dynamic has no influence are challenged in this experience-based commentary.

Fan-shaped gold nanoantennas above reflective substrates for surface-enhanced infrared absorption (SEIRA).

Here, we report a new nanoantenna for surface-enhanced infrared absorption (SEIRA) detection, consisting of a fan-shaped Au structure positioned at a well-specified distance above a reflective plane with an intervening silica spacer layer. We examine how to optimize both the antenna dimensions and the spacer layer for optimal SEIRA enhancement of the C-H stretching mode. This tunable 3D geometry yields a theoretical SEIRA enhancement factor of 10(5), corresponding to the experimental detection of 20-200 zeptomoles of octadecanethiol, using a standard commercial FTIR spectrometer.

Targeting pancreatic cancer with magneto-fluorescent theranostic gold nanoshells.

Aim: We report a magneto-fluorescent theranostic nanocomplex targeted to neutrophil gelatinase-associated lipocalin (NGAL) for imaging and therapy of pancreatic cancer.

Materials & Methods: Gold nanoshells resonant at 810 nm were encapsulated in silica epilayers doped with iron oxide and the near-infrared (NIR) dye indocyanine green, resulting in theranostic gold nanoshells (TGNS), which were subsequently conjugated with antibodies targeting NGAL in AsPC-1-derived xenografts in nude mice.

Results: Anti-NGAL-conjugated TGNS specifically targeted pancreatic cancer cells in vitro and in vivo providing contrast for both NIR fluorescence and T2-weighted MRI with higher tumor contrast than can be obtained using long-circulating, but nontargeted, PEGylated nanoparticles.

Narrowband photodetection in the near-infrared with a plasmon-induced hot electron device.

In gratings, incident light can couple strongly to plasmons propagating through periodically spaced slits in a metal film, resulting in a strong, resonant absorption whose frequency is determined by the nanostructure periodicity. When a grating is patterned on a silicon substrate, the absorption response can be combined with plasmon-induced hot electron photocurrent generation. This yields a photodetector with a strongly resonant, narrowband photocurrent response in the infrared, limited at low frequencies by the Schottky barrier, not the bandgap of silicon.

Surface-enhanced infrared absorption using individual cross antennas tailored to chemical moieties.

The development of antenna structures for surface-enhanced infrared absorption spectroscopy (SEIRA) is a topic of intense and growing interest for extending IR spectroscopy to zeptomolar quantities and ultimately to the single-molecule level. Here we show that strong infrared spectroscopic enhancements can be obtained from individual gold nanoantennas using conventional IR spectrometric sources. The antenna structure dimensions can be tuned to enhance the IR modes of specific chemical moieties.

Hot electrons do the impossible: plasmon-induced dissociation of H2 on Au.

Heterogeneous catalysis is of paramount importance in chemistry and energy applications. Catalysts that couple light energy into chemical reactions in a directed, orbital-specific manner would greatly reduce the energy input requirements of chemical transformations, revolutionizing catalysis-driven chemistry. Here we report the room temperature dissociation of H(2) on gold nanoparticles using visible light.

Manipulating magnetic plasmon propagation in metallic nanocluster networks.

Neighboring fused heptamers can support magnetic plasmons due to the generation of antiphase ring currents in the metallic nanoclusters. In this paper, we use such artificial plasmonic molecules as basic elements to construct low-loss plasmonic waveguides and devices. These magnetic plasmon-based complexes exhibit waveguiding functionalities including plasmon steering over large-angle bends, splitting at intersections, and Mach-Zehnder interference between consecutive Y-splitters.

Magnetic plasmon formation and propagation in artificial aromatic molecules.

The plasmonic properties of coupled metallic nanostructures are understood through the analogy between their collective plasmon modes and the electronic orbitals of corresponding molecules. Here we expand this analogy to planar arrangements of plasmonic nanostructures whose magnetic plasmons directly resemble the delocalized orbitals of aromatic hydrocarbon molecules. The heptamer structure serves as a benzene-like building block for a family of plasmonic artificial aromatic analogs with fused ring structures.

Light-induced release of DNA from gold nanoparticles: nanoshells and nanorods.

Plasmon-resonant nanoparticle complexes show highly promising potential for light-triggered, remote-controlled delivery of oligonucleotides on demand, for research and therapeutic purposes. Here we investigate the light-triggered release of DNA from two types of nanoparticle substrates: Au nanoshells and Au nanorods. Both light-triggered and thermally induced release are distinctly observable from nanoshell-based complexes, with light-triggered release occurring at an ambient solution temperature well below the DNA melting temperature.

Heterodimers: plasmonic properties of mismatched nanoparticle pairs.

Heterodimers-two closely adjacent metallic nanoparticles differing in size or shape-exemplify a simple nanoscale geometry that gives rise to a remarkably rich set of properties. These include Fano resonances, avoided crossing behavior, and a surprising dependence of the scattering spectrum on the direction of excitation, known as the "optical nanodiode" effect. In a series of studies, we experimentally probe and theoretically analyze these properties in heterodimer nanostructures, where nanoparticle size and plasmon resonance frequency are varied systematically.