Predicting nonlinear physical aging of glasses from equilibrium relaxation via the material time.

The noncrystalline glassy state of matter plays a role in virtually all fields of materials science and offers complementary properties to those of the crystalline counterpart. The caveat of the glassy state is that it is out of equilibrium and therefore exhibits physical aging, i.e.

Time-scale ordering in hydrogen- and van der Waals-bonded liquids.

The time scales of structural relaxation are investigated on the basis of five different response functions for 1,2, 6-hexanetriol, a hydrogen-bonded liquid with a minor secondary contribution, and 2,6,10,15,19,23-hexamethyl-tetracosane (squalane), a van der Waals-bonded liquid with a prominent secondary relaxation process. Time scales of structural relaxation are derived as inverse peak frequencies for each investigated response function. For 1,2,6-hexanetriol, the ratios of the time scales are temperature-independent, while a decoupling of time scales is observed for squalane in accordance with the literature.

Generalized single-parameter aging tests and their application to glycerol.

Physical aging of glycerol following temperature jumps is studied by dielectric spectroscopy at temperatures just below the glass transition temperature. The data are analyzed using two single-parameter aging tests developed by Hecksher et al. [J.

Communication: High pressure specific heat spectroscopy reveals simple relaxation behavior of glass forming molecular liquid.

The frequency dependent specific heat has been measured under pressure for the molecular glass forming liquid 5-polyphenyl-4-ether in the viscous regime close to the glass transition. The temperature and pressure dependences of the characteristic time scale associated with the specific heat is compared to the equivalent time scale from dielectric spectroscopy performed under identical conditions. It is shown that the ratio between the two time scales is independent of both temperature and pressure.

Communication: Two measures of isochronal superposition.

A liquid obeys isochronal superposition if its dynamics is invariant along the isochrones in the thermodynamic phase diagram (the curves of constant relaxation time). This paper introduces two quantitative measures of isochronal superposition. The measures are used to test the following six liquids for isochronal superposition: 1,2,6 hexanetriol, glycerol, polyphenyl ether, diethyl phthalate, tetramethyl tetraphenyl trisiloxane, and dibutyl phthalate.