Spectrochim Acta A Mol Biomol Spectrosc
March 2024
Here we report the highly efficient upconversion luminescence (UCL) and optical temperature sensing based on the novel host of KYb(MoO) doped with trivalent lanthanide (Ln) ions at 980 nm excitation. The high Yb concentration and unique ordered layer structure in KYb(MoO) host are beneficial for the enhancement of UCL efficiency by improving the absorption and the negative migration of excitation energy. Ho, Er, and Tm ions were selected to singly dope the KYb(MoO) host, achieving three primary colors of red, green, blue UCL, respectively.
View Article and Find Full Text PDFHerein, a facile one-step electrodeposition route was presented for preparing NiS/NiS composite film on Ni foam substrate (denoted as NiS/NF). The NiS granular film is composed of mangy interconnected ultra-thin NiS nanoflakes with porous structures. When applied as electrodes for supercapacitors, the ultra-thin nanoflakes can provide more active sites for redox reaction, and the interconnected porous structure has an advantage for electrolyte ions to penetrate into the inner space of active materials quickly.
View Article and Find Full Text PDFThe goals of this study were to bring forward new data and insights into the effect of activation methods, operational variables and reaction pathways during sulfate radicals-based oxidation of benzophenone-3 (BP-3) in aqueous solution. Heat, transition metal ions (Fe, Cu, Co), UV and visible light irradiation were used to activate persulfate (PS) to degrade BP-3. The results showed that these three activation methods can remarkably enhance BP-3 removal efficiency.
View Article and Find Full Text PDFWith the increasing applications of carbon nanotubes (CNTs) worldwide, considerable concerns have been raised regarding their inevitable releases into natural waters and ecotoxicity. It was supposed that CNTs may interact with some existing pollutants like zinc in aquatic systems and exhibit different effects when compared with their single treatments. However, data on their possible combined toxicity on aquatic species are still lacking.
View Article and Find Full Text PDFAs one of the first generation of fluoroquinolone antibiotics, flumequine (FLU) has been detected ubiquitously in surface waters and municipal wastewaters. In light of FLU's possible adverse effects on aquatic species, the removal of this antibiotic has received worldwide attention. In this study, the kinetics, transformation products, mechanisms and toxicity variations of the ozonation process for FLU were systematically determined.
View Article and Find Full Text PDFPerfluorooctane sulfonate (PFOS) and zinc have been detected in aquatic environment widely. In order to study the combined effects of PFOS and Zn, a series of experiments was conducted to explore the acute mortality, bioaccumulation and antioxidant status of Limnodrilus hoffmeisteri. The acute toxicity was evaluated by calculating 24h-EC50 values, and it was observed that 24h-EC50 values in single and joint treatments decreased with decreasing pH value or increasing exposure concentration.
View Article and Find Full Text PDFThe aim of the current study was to investigate the possible correlation between the C677T methylenetetrahydrofolate reductase (MTHFR) polymorphism and venous thromboembolism (VTE) in a population-based case-control study. Homocysteine (Hcy) was quantified by Abbott IMx immunoassay; screening for C677T MTHFR substitution was performed by polymerase chain reaction (PCR) and restriction analysis. The results from the two groups (440 patients and 440 controls) revealed that the frequency of T alleles and TT carriers was significantly higher in patients compared with that of the healthy controls.
View Article and Find Full Text PDF