Exploring the Effect Mechanism of Alkyl Chain Lengths on the Tribological Performance of Ionic Liquids.

In this work, four kinds of imidazole phosphate ionic liquids (ILs) with different anionic and cationic alkyl chain lengths were synthesized. The physicochemical properties and tribological performance of ILs were evaluated. The experimental results revealed that the tribological properties of ILs were positively correlated with the cationic chain length and negatively correlated with the anionic chain length.