Novel carboxymethyl cellulose-based hydrogel embedded with metal organic framework for efficient cationic dye removal from water.

The rGO/CMC/β-CD (RCβ) hydrogel was synthesized from reduced graphene oxide (rGO), β-cyclodextrin (β-CD) and sodium carboxymethyl cellulose (CMC) by radical polymerization. A novel hydrogel adsorbent was created by growing the metal-organic framework (Cu-BTC) in-situ on RCβ hydrogel, which has excellent adsorption capacities for cationic dyes in wastewater. The adsorption parameters such as the amount of adsorbent, pH of solution and adsorption time were optimized through batch adsorption experiments.

Adsorption properties of cellulose/guar gum/biochar composite hydrogel for Cu, Co and methylene blue.

Herein, Typha angustifolia was used as a charcoal source and chemically modified with a strong oxidizing agent, potassium permanganate (KMnO), to obtain modified Typha angustifolia (MTC). Then, the green, stable and efficient CMC/GG/MTC composite hydrogel was successfully prepared by compounding MTC with carboxymethyl cellulose (CMC) and guar gum (GG) by free radical polymerization. Various variables that influence adsorption performance were explored, and optimal adsorption conditions were determined.

Chitosan-based composite microspheres for treatment of hexavalent chromium and EBBR from aqueous solution.

Hexavalent chromium is widely used in industrial fields, but its pollution has posed a great threat to the environment due to its high toxicity. We created a chitosan-based microsphere biosorbent (CP) by combining polyethyleneimine with chitosan adopting inverse emulsion polymerization method. Under the optimal conditions (pH = 3), the maximum adsorption capacity of composite microspheres can reach 299.