For developing commercially viable LiNiMnCoO (NCM), it is necessary to alleviate the irreversible chemical process upon Li-ion insertion/extraction, which primarily accounts for prevailing capacity loss, impedance buildup as well as low columbic efficiency. To resolve this issue, we herein propose a simple but novel method to alter the chemical composition by a facile treatment of HO, which remarkably reduces the cation mixing of Li/Ni and residual lithium on the cathode. The tailored composition contributes great resistance to the structural reconstruction and enhancement in structural reversibility, as shown by Raman and high-resolution transmission electron microscope (HRTEM) results.
View Article and Find Full Text PDFWith urgent desire of promoting sustainable development, this study explored the impact and affecting mechanism of green credit on green economy efficiency through spatial lag model. Panel data from 2008 to 2019 of 30 selected provinces and cities in China were collected to portray the green economy efficiency with application of Sup-SBM DEA including unexpected outputs. The results show that (1) green credit had significant promoting effect on green economy efficiency, while time-space inconsistency existed.
View Article and Find Full Text PDFA SiC ceramic coating was prepared on carbon/carbon composites by pack cementation. The phase composition and microstructure of the coated specimens were characterized using X-ray diffraction instrument and scanning electron microscope. The results showed that the mass-loss percentage of the coated specimen was 9.
View Article and Find Full Text PDFIn order to achieve the highly efficient preparation of high-performance carbon/carbon (C/C) composites, epitaxial grown carbon nanotubes (CNTs) and a pyrocarbon matrix were simultaneously synthesized to fabricate CNT-reinforced C/C composites (CC/C composites). With precise control of the temperature gradient, CNTs and the pyrocarbon matrix could grow synchronously within a 2D needle-punched carbon fiber preform. Surprisingly, the CNTs remained intact within the pyrocarbon matrix at the nano-level, and the CNT-reinforced nano-pyrocarbon matrix was compact, with virtually no gaps and pores, which were tightly connected with the carbon fibers without cracks.
View Article and Find Full Text PDFOptically bright lead halide perovskite nanocrystals of different morphologies ranging from nanocubes to flat nanoplatelets to elongated nanowires have been reported. The morphology of the nanocrystals is expected to affect various properties such as the band edge energy and the electron-hole exchange interaction. However, aside from nanocubes, the investigation of optical properties in the lead halide perovskite nanocrystals of different morphologies at the single emitter level has been lacking.
View Article and Find Full Text PDFAn in-situ, catalyst-free method for synthesizing 3C-SiC ceramic nanowires (SiCNWs) inside carbon⁻carbon (C/C) composites was successfully achieved. Obtained samples in different stages were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), and Raman scattering spectroscopy. Results demonstrated that the combination of sol-gel impregnation and carbothermal reduction was an efficient method for in-situ SiCNW synthesis, inside C/C composites.
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