ACS Appl Mater Interfaces
August 2021
Composite electrolytes (CE) combining a ceramic filler and a polymer matrix is an effective way to enhance battery safety. But the increased ceramic filler mass fraction decreases the flexibility, which increases the interfacial resistance. To alleviate interfacial resistance further, a gradient composite electrolyte (GCE) using a Sc, Ge-doped NaZrSiPO (NZSP) as the ceramic filler and poly(ethylene oxide) (PEO) as the polymer matrix is proposed.
View Article and Find Full Text PDFLithium-sulfur batteries (LSBs) have a high theoretical energy density and are low cost. However, the undesirable shuttle effect with the solid discharge product, Li2S, greatly impedes their market penetration. Conductive carbon materials with functional elements are beneficial in controlling the shuttle effect and can reactivate the Li2S, leading to improved long term cycling performance of LSBs.
View Article and Find Full Text PDFJ Phys Chem Lett
January 2021
Alternative battery technologies are required to meet growing energy demands and to solve the limitations of the present energy technologies. As such, it is necessary to look beyond lithium-ion batteries. Zinc batteries enable high power density while being sourced from abundant and cost-effective materials.
View Article and Find Full Text PDFRecently, SnP has emerged as a promising anode for sodium-ion batteries (SIBs) due to the high specific capacity. However, the use of SnP has been impeded by capacity fade and an inferior rate performance. Herein, a biomimetic heterostructure is reported by using a simple hydrothermal reaction followed by thermal treatment.
View Article and Find Full Text PDFLi-S batteries (LSBs) require a minimum 6 mAh cm areal capacity to compete with the state-of-the-art lithium ion batteries (LIBs). However, this areal capacity is difficult to achieve due to a major technical issue-the shuttle effect. Nonpolar carbon materials limit the shuttle effect through physical confinement.
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