Photocatalytic CO2 reduction to produce C2 products remains a challenge. Herein, Cu2O@Cu@NiAl-LDH composites with three-dimensional ordered core-shell structures were successfully prepared, and the effects of Cu2O with different exposed surfaces on CO2 photoreduction were investigated. The synergistic effect of zero-valent Cu and Cu+ as intermediate electron mediators retains more photogenerated electrons.
View Article and Find Full Text PDFThe quest for sustainable photocatalytic CO reduction reactions (CRR) emphasizes the development of high-efficiency, economically viable, and durable photocatalysts. A novel approach involving the synthesis of Bi-CDs/LDH heterojunctions, incorporating plasma metals and carbon quantum dots via hydrothermal and co-precipitation methods, yields remarkable results. The optimized BCL-4 photocatalyst demonstrates exceptional performance, with CH and CH yields of 1.
View Article and Find Full Text PDFTransforming CO into renewable fuels or valuable carbon compounds could be a practical means to tackle the issues of global warming and energy crisis. Photocatalytic CO reduction is more energy-efficient and environmentally friendly, and offers a broader range of potential applications than other CO conversion techniques. Ferroelectric materials, which belong to a class of materials with switchable polarization, are attractive candidates as catalysts due to their distinctive and substantial impact on surface physical and chemical characteristics.
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