Multivalence-State Tungsten Species Facilitated Iridium Loading for Robust Acidic Water Oxidation.

The development of the proton exchange membrane water electrolyzer (PEMWE) is still limited by the prohibitive cost and scarcity of iridium (Ir)-based oxygen evolution reaction (OER) catalyst. This work presents a novel catalyst synthesized by precursor-atomization and rapid joule-heating method, successfully doping iridium atoms into polyvalent tungsten blends (W, W, W) based on titanium substrate. The vacancy engineering of unsaturated tungsten oxide (W, W) reconstructs the electronic structure of the catalyst surface, which resulting in the low-valence state iridium species, avoiding excessive oxidation of iridium and accelerating the catalytic kinetics.

Reactive membranes for groundwater remediation of chlorinated aliphatic hydrocarbons: competitive dechlorination and cost aspects.

A nanocomposite membrane incorporating reactive Pd-Fe nanoparticles (NPs) was developed to remediate chlorinated aliphatic hydrocarbons (CAHs) from groundwater. Other than recapturing the produced Fe for in-situ regeneration, the functionalized polyanions prevented NPs agglomeration and resulting in a spherical Fe core (55 nm, O/Fe = 0.05) and an oxidized shell (4 nm, O/Fe = 1.

High-Valence-Manganese Driven Strong Anchoring of Iridium Species for Robust Acidic Water Oxidation.

Designing an efficient and durable electrocatalyst for the sluggish anodic oxygen evolution reaction (OER) has been the primary goal of using proton exchange membrane electrolyzer owing to the highly acidic and oxidative environment at the anode. In this work, it is reported that high-valence manganese drives the strong anchoring of the Ir species on the manganese dioxide (MnO ) matrix via the formation of an Mn-O-Ir coordination structure through a hydrothermal-redox reaction. The iridium (Ir)-atom-array array is firmly anchored on the Mn-O-Ir coordination structure, endowing the catalyst with excellent OER activity and stability in an acidic environment.

Anchoring Ni/NiO heterojunction on freestanding carbon nanofibers for efficient electrochemical water oxidation.

Rational design of low-cost and efficient electrocatalyst for the anodic oxygen evolution reaction (OER) to replace noble-metal-based catalysts is greatly desired for the large-scale application of water electrocatalysis. And compared with the conventional powdery catalysts, the freestanding electrode architecture is more attractive owing to the enhanced kinetics and stability. In this work, we report an electrospinning-carbonization-post oxidation strategy to develop the freestanding N-doped carbon nanofibers anchored with Ni/NiO nanoparticles (denoted as Ni/NiO-NCNFs) as efficient OER electrocatalyst.

Multiscale Engineering of Nonprecious Metal Electrocatalyst for Realizing Ultrastable Seawater Splitting in Weakly Alkaline Solution.

Seawater electrolysis is an attractive technique for mass production of high-purity hydrogen considering the abundance of seawater. Nevertheless, due to the complexity of seawater environment, efficient anode catalyst, that should be, cost effective, highly active for oxygen evolution reaction (OER) but negligible for Cl /ClO formation, and robust toward chlorine corrosion, is urgently demanded for large-scale application. Although catalysis typically appears at surface, while the bulk properties and morphology structure also have a significant impact on the performance, thus requiring a systematic optimization.

Effect and safety of traditional Chinese exercises for patients with type 2 diabetes: A protocol for systematic review and network meta-analysis.

Background: Traditional Chinese exercises are more and more popular for type 2 diabetes patients for the treatment and rehabilitation; however, the comparative effectiveness and safety remains unclear. Our study aims to compare the pros and cons of these exercise interventions for type 2 diabetes by implementing a network meta-analysis.

Methods: Eight databases will be searched for relevant systematic reviews including SinoMed, VIP, CNKI, Wanfang, PubMed, Embase, Web of Science and the Cochrane Library from inception to Oct 2021.

Comparative Microbial Profiles of Colonic Digesta between Ningxiang Pig and Large White Pig.

Sixteen 35-day-old piglets, including eight Large White (LW) piglets (a lean-type pig breed) and eight Ningxiang (NX) piglets (a fatty-type Chinese Indigenous pig breed), were fed the same diet for 105 days. NX pigs had higher intramuscular fat content than LW pigs ( < 0.05).

Carbon hollow fiber membranes for a molecular sieve with precise-cutoff ultramicropores for superior hydrogen separation.

Carbon molecular sieve (CMS) membranes with rigid and uniform pore structures are ideal candidates for high temperature- and pressure-demanded separations, such as hydrogen purification from the steam methane reforming process. Here, we report a facile and scalable method for the fabrication of cellulose-based asymmetric carbon hollow fiber membranes (CHFMs) with ultramicropores of 3-4 Å for superior H separation. The membrane fabrication process does not require complex pretreatments to avoid pore collapse before the carbonization of cellulose precursors.

Sandstorm weather is a risk factor for mortality in ischemic heart disease patients in the Hexi Corridor, northwestern China.

Ischemic heart disease (IHD) is one of the leading causes of mortality worldwide. Moreover, the effects of air pollution have been associated with several cardiovascular diseases (CVDs). The relationship between sandstorm weather and IHD is unknown.

Spinning Cellulose Hollow Fibers Using 1-Ethyl-3-methylimidazolium Acetate⁻Dimethylsulfoxide Co-Solvent.

The mixture of the ionic liquid 1-ethyl-3-methylimidazolium acetate (EmimAc) and dimethylsulfoxide (DMSO) was employed to dissolve microcrystalline cellulose (MCC). A 10 wt % cellulose dope solution was prepared for spinning cellulose hollow fibers (CHFs) under a mild temperature of 50 °C by a dry⁻wet spinning method. The defect-free CHFs were obtained with an average diameter and thickness of 270 and 38 µm, respectively.