Biocoke has the potential to reduce the fossil-based materials in metallurgical processes, along with mitigating anthropogenic CO- and greenhouse gas (GHG) emissions. Reducing those emissions is possible by using bio-based carbon, which is CO-neutral, as a partial replacement of fossil carbon. In this paper, the effect of adding 5, 10, 15, 30, and 45 wt.
View Article and Find Full Text PDFThe paper presents a method for obtaining electrochemically active ultrafine composites of iron oxides, superparamagnetic 'core/shell' γ-FeO/defective α-FeO, which involved modifying sol-gel citrate synthesis, hydrothermal treatment of the formed sol, and subsequent annealing of materials in the air. The synthesized materials' phase composition, magnetic microstructure, and structural, morphological characteristics have been determined via X-ray analysis, Mossbauer spectroscopy, scanning electron microscopy (SEM), and adsorption porometry. The mechanisms of phase stability were analyzed, and the model was suggested as FeOOH → γ-FeO → α-FeO.
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