Supported CuO-CeO catalysts have been extensively studied for their outstanding catalytic activity in CO oxidation. Unfortunately, they are prone to sintering and deactivation when exposed to high-temperature automotive exhausts. Herein, taking advantage of the heat-resistant SiO microspheres, we fabricated a series of core-shell-structured yCuO- xCeO@SiO ( x is the weight ratio of CeO-SiO and y is the weight ratio of Cu-(CeO@SiO)) composite catalysts.
View Article and Find Full Text PDFA low-concentration cobalt (∼6 at%) and manganese (∼3 at%) bimetallic oxide catalyst supported on ceria nanorods (CoMnO/CeO), as well as its related single metal oxide counterparts (CoO/CeO and MnO/CeO) was synthesized via a deposition-precipitation approach. The fresh samples after air-calcination at 400 °C were tested under the reaction conditions of CO oxidation, and showed the following order of reactivity: CoMnO/CeO > CoO/CeO > MnO/CeO. X-ray diffraction (XRD) and transmission electron microscopy (TEM) data identified that the structure of the CeO support was maintained during deposition of metal (Co, Mn) ions while the corresponding vis-Raman spectra verified that more oxygen vacancies were created after deposition-precipitation than those in pure ceria nanorods.
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