A novel geometry for electroluminescent devices, which does not require transparent electrodes for electrical input, is demonstrated, theoretically analyzed, and experimentally characterized. Instead of emitting light through a conventional electrode, light emission occurs through a polar liquid or solid and input electrical electrodes are coplanar, rather than stacked in a sandwich configuration. This new device concept is scalable and easily deployed for a range of modular alternating-current-powered electroluminescent light sources and light-emitting sensing devices.
View Article and Find Full Text PDFDuring our investigation of perovskite solar cell materials, we serendipitously discovered an unusual photoconductive property of polyiodide, which can be enhanced greatly through the interaction of in situ-formed polyiodide and 3-thiophenemethylamine salt. This communication examined the photoconductive properties of polyiodide with and without adding different aromatic methylamine compounds. MATPI2 exhibits a high photoconductivity and short response time.
View Article and Find Full Text PDFWhite-light-emitting materials with high mobility are necessary for organic white-light-emitting transistors, which can be used for self-driven OLED displays or OLED lighting. In this study, we combined two materials with similar structures-2-fluorenyl-2-anthracene (FlAnt) with blue emission and 2-anthryl-2-anthracence (2A) with greenish-yellow emission-to fabricate OLED devices, which showed unusual solid-state white-light emission with the CIE coordinates (0.33, 0.
View Article and Find Full Text PDFThree new spirofluorene-based hole transport materials, Spiro-S, Spiro-N, and Spiro-E, are synthesized by replacing the -methoxy substituent in 2,2',7,7'-tetrakis(,-di--methoxyphenylamine)-9,9'-spirobifluorene (Spiro-MeOTAD) with methylsulfanyl, ,-dimethylamino and ethyl groups. Their properties as hole transport materials in perovskite solar cells are investigated. The impact of replacing the -methoxy substituent on bulk properties, such as the photophysical properties, HOMO/LUMO energy level, hole extraction properties and morphologies of perovskite thin films are investigated.
View Article and Find Full Text PDFMacromol Rapid Commun
August 2016
Organic electrochromic materials change color rapidly under applied potential. A butterfly-shaped compound, 5,5',-5″,-5'″-(thieno[3,2-b]thiophene-2,3,5,6-tetrayl) tetrakis-(2,3-dihydrothieno[3,4-b][1,4]dioxine) (t-EDOT-TT) is synthesized for the first time and polymerized at different potentials via electropolymerization technique. By applying different polymerization potentials, the optical and electrochromic properties of this newly synthesized polymer can be tuned.
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