In the presented work, the properties of carbon materials obtained in the reaction of sodium bicarbonate (C-SB) and ammonium oxalate (C-AO) with magnesium by combustion synthesis were investigated. For the materials obtained in this way, the influence of the type of precursor on their properties was analyzed, including: Degree of crystallinity, porous structure, surface topography, and electrochemical properties. It has been shown that the products obtained in magnesiothermic process were found to contain largely the turbostratic carbon forming a petal-like graphene material.
View Article and Find Full Text PDFThree carbon materials with a highly diversified structure and at the same time much less different porosity were selected for the study: single-walled carbon nanotubes, heat-treated activated carbon, and reduced graphene oxide. These materials were used for the adsorption of 2,4-D herbicide from aqueous solutions and in its electroanalytical determination. Both the detection of this type of contamination and its removal from the water are important environmental issues.
View Article and Find Full Text PDFThe paper presents the results of studies on the modeling and optimization of organic pollutant removal from an aqueous solution in the course of simultaneous adsorption onto activated carbons with varied physical characteristics and oxidation using HO. The methodology for determining the models used for predicting the sorption and catalytic parameters in the process was presented. The analysis of the influence of the sorption and catalytic parameters of activated carbons as well as the oxidizer dose on the removal dynamics of organic dyes-phenol red and crystal violet-was carried out based on the designated empirical models.
View Article and Find Full Text PDFJ Hazard Mater
July 2003
This paper discusses the increasing use of activated carbons to remove wastewater contaminants and their contribution to producing wastes abundant in heavy metals. Considering their threat to the environment and their possible recovery, research on the regeneration of spent carbon sorbents and catalysts is advisable. It has also been shown that it is possible to recover activated carbon from spent catalyst (CC(spent)) generated by vinyl acetate synthesis by using supercritical extraction with carbon dioxide or by leaching with hydrochloric acid or a solution of nitric acid assisted by microwave energy.
View Article and Find Full Text PDF