Effective plasmon coupling in conical cavities for sensitive surface enhanced Raman scattering with quantitative analysis ability.

Conical silver nanocavity arrays are fabricated by directly depositing Ag on porous alumina templates with V-shaped nanopores. By controlling the thickness of deposited Ag, complete and cracked cavity arrays are constructed respectively. The cracked cavity arrays with the cavity wall consisting of Ag nanoparticles are demonstrated to exhibit higher surface enhanced Raman scattering (SERS) activity than the complete one.