The latest synthesized monolayer (ML) MoSiN material exhibits stability in ambient conditions, suitable bandgap, and high mobilities. Its potential as a next-generation transistor channel material has been demonstrated through quantum transport simulations. However, in practical two-dimensional (2D) material transistors, the electrical contacts formed by the channel and the electrode must be optimized, as they are crucial for determining the efficiency of carrier injection.
View Article and Find Full Text PDFACS Appl Mater Interfaces
April 2024
Ultrathin oxide semiconductors are promising candidates for back-end-of-line (BEOL) compatible transistors and monolithic three-dimensional integration. Experimentally, ultrathin indium oxide (InO) field-effect transistors (FETs) with thicknesses down to 0.4 nm exhibit an extremely high drain current (10 μA/μm) and transconductance (4000 μS/μm).
View Article and Find Full Text PDFWe conduct a comprehensive theoretical analysis of wurtzite GaInN ternary alloys, focusing on their structural, electronic, elastic, piezoelectric, and dielectric properties through rigorous first-principles calculations. Our investigation systematically explores the influence of varying Ga composition ( = 0%, 25%, 50%, 75%, 100%) on the alloy properties. Remarkably, we observe a distinctive non-linear correlation between the band gap and Ga concentration, attributable to unique slopes in the absolute positions of the valence band maximum and conduction band minimum with respect to Ga concentration.
View Article and Find Full Text PDFAdvanced mRNA vaccines play vital roles against SARS-CoV-2. However, most current mRNA delivery platforms need to be stored at -20 °C or -70 °C due to their poor stability, which severely restricts their availability. Herein, we develop a lyophilization technique to prepare SARS-CoV-2 mRNA-lipid nanoparticle vaccines with long-term thermostability.
View Article and Find Full Text PDFRecently, a topological-to-trivial insulator quantum-phase transition induced by an electric field has been experimentally reported in monolayer (ML) and bilayer (BL) NaBi. A narrow ML/BL NaBi nanoribbon is necessary to fabricate a high-performance topological transistor. By using the density functional theory method, we found that wider ML NaBi nanoribbons (>7 nm) are topological insulators, featured by insulating bulk states and dissipationless metallic edge states.
View Article and Find Full Text PDFMonolayer (ML) MoS2 is one of the most extensively studied two-dimensional (2D) semiconductors. However, it suffers from low carrier mobility and pervasive Schottky contact with metal electrodes. 2D semiconductor Bi2O2S, a sulfur analogue of 2D Bi2O2Se, has been prepared recently.
View Article and Find Full Text PDFThe successful fabrication of sub-5 nm 2D MoS field-effect transistors (FETs) announces the approaching post-silicon era. It is possible for tunneling field-effect transistors (TFETs) based on monolayer black phosphorene (ML BP) to work well in the sub-5 nm region because of its moderate direct band gap, anisotropic electronic properties and high carrier mobility. We simulate the device performance limit of the ML BP TFETs at the sub-5 nm scale using ab initio quantum transport calculations.
View Article and Find Full Text PDFNitrogen-doped graphene was synthesized by simple photoreduction of graphene oxide (GO) deposited on nickel foam under NH3 atmosphere. The combination of photoreduction and NH3 not only reduces the GO in a shorter time but also induces nitrogen doping easily. The nitrogen doped content of N-rGO@NF reaches a high of 5.
View Article and Find Full Text PDFHere, a novel graphene composite foam with 3D lightweight continuous and interconnected nickel network was successfully synthesized by hydroiodic (HI) acid using nickel foam as substrate template. The graphene had closely coated on the backbone of the 3D nickel conductive network to form nickel network supported composite foam without any polymeric binder during the HI reduction of GO process, and the nickel conductive network can be maintained even in only a small amount of nickel with 1.1 mg/cm(2) and had replaced the traditional current collector nickel foam (35 mg/cm(2)).
View Article and Find Full Text PDFHere we report a simple strategy to prepare three-dimensional graphene gel coated on nickel foam for supercapacitor applications by a simple 'dipping and drying' process. The supercapacitors based on three-dimensional graphene gel (G-gel@NF-1) exhibited high rate capability of 152 F g(-1) at 0.36 A g(-1) and 107 F g(-1) at 90.
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