Core-shell particle formation co-assembly of AB diblock copolymers and nanoparticles in 3D soft confinement was studied using a simulated annealing method. Several sequences of soft confinement-induced core-shell particles were predicted as functions of the volume fraction of the nanoparticle to core-shell particles, the incompatibility between blocks, the volume fractions of A-blocks, the chain length of AB diblocks, the eccentricity of the nanoparticle, and the initial concentration of copolymers. Simulation results demonstrate that those factors are able to tune the morphology of the core-shell particles precisely.
View Article and Find Full Text PDFThe soft confinement-induced self-assembly of AB diblock copolymers on a nanocylinder is studied via a simulated annealing method. The formation of multiple copolymer shells was predicted by varying the interfacial interaction, the size of confinement, and the height and diameter of the nanocylinder. The competition between solvent repulsion and nanocylinder attraction determined the degree of encapsulation of the copolymer shell.
View Article and Find Full Text PDFThe self-assembly of block copolymers on nanocylinders has attracted a lot of interest due to its potential application in biomedicine and other fields. In this study, the self-assembly phase behavior of AB diblock copolymers on long nanocylinders in soft confinement has been studied by using a simulated annealing method. A square phase diagram of the morphology was constructed by increasing the number of chains of copolymers (cn) and the cylindrical diameter ().
View Article and Find Full Text PDFIn recent years, more attention has been paid to the application of cold plasma (CP) in eliminating foodborne pathogenic bacteria. This work investigated CP effects on inactivation kinetics and cell envelopes of Listeria monocytogenes (L. monocytogenes) and Salmonella Enteritidis (S.
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