A Better Choice to Achieve High Volumetric Energy Density: Anode-Free Lithium-Metal Batteries.

Volumetric energy density is a critical but easily neglected index of lithium-metal batteries (LMBs). Compared with gravimetric energy density, the volumetric energy density (VED) of LMBs is much more sensitive to the anode/cathode (A/C) ratio due to the low density of lithium (Li) metal and the volume expansion of the Li-metal anode owing to its pulverization during cycles. Anode-free LMBs (AF-LMBs) have high theoretical VED due to the absence of an anode and high retention with relatively low cell expansion.

Li-Rich Li [Ni Co Mn ]O for Anode-Free Lithium Metal Batteries.

Anode-free lithium metal batteries can maximize the energy density at the cell level. However, without the Li compensation from the anode side, it faces much more challenging to achieve a long cycling life with a competitive energy density than Li metal-based batteries. Here, we prolong the lifespan of an anode-free Li metal battery by introducing Li-rich Li [Ni Co Mn ]O into the cathode as a Li-ions extender.

Mesoporous Amorphous Silicon: A Simple Synthesis of a High-Rate and Long-Life Anode Material for Lithium-Ion Batteries.

Amorphous Si (a-Si) shows potential advantages over crystalline Si (c-Si) in lithium-ion batteries, owing to its high lithiation potential and good tolerance to intrinsic strain/stress. Herein, porous a-Si has been synthesized by a simple process, without the uses of dangerous or expensive reagents, sophisticated equipment, and strong acids that potential cause environment risks. These porous a-Si particles exhibit excellent electrochemical performances, owing to their porous structure, amorphous nature, and surface modification.