The nature of fatty acid interaction with a polyelectrolyte-surfactant pair revealed by NMR spectroscopy.

The interaction mechanisms of an oppositely charged polyelectrolyte-surfactant pair and dodecanoic (lauric) acid (LA) were experimentally investigated using a combination of nuclear magnetic resonance (NMR) techniques. It is observed that LA significantly affects the interaction between the anionic surfactant sodium dodecylethersulfate (SDES) and the cationic polymer guar modified with grafted hydroxypropyl trimethylammonium chloride (Jaguar C13 BF). Typically, oppositely charged polymers and surfactants interact electrostatically at a certain surfactant concentration known as the critical aggregation concentration (CAC).