Secondary organic aerosol formation from evaporated biofuels: comparison to gasoline and correction for vapor wall losses.

With an ongoing interest in displacing petroleum-based sources of energy with biofuels, there is a need to measure and model the formation and composition of secondary organic aerosol (SOA) from organic compounds present in biofuels. We performed chamber experiments to study SOA formation from four recently identified biofuel molecules and mixtures and commercial gasoline under high NOx conditions: diisobutylene, cyclopentanone, an alkylfuran mixture, and an ethanol-to-hydrocarbon (ETH) mixture. Cyclopentanone and diisobutylene had a significantly lower potential to form SOA compared to commercial gasoline, with SOA mass yields lower than or equal to 0.