Effects of transition metal substitution doping on the structure and magnetic properties of biphenylene.

This study employed first-principles calculations to comprehensively explore the structural, electronic, and magnetic properties of transition metal-doped biphenylene networks (BPNs). Initially, we optimized the most stable structures of biphenylene doped with various transition metals (Sc, Ti, V, Cr, Mn, Fe, Co, Ni, Cu, and Zn) and analysed their doping energies and electronic structures in detail. The results indicate that the introduction of transition metals induces varying degrees of spin polarization.

Microtopography effects on pedogenesis in the mudstone-derived soils of the hilly mountainous regions.

Topography is a critical factor that determines the characteristics of regional soil formation. Small-scale topographic changes are referred to microtopographies. In hilly mountainous regions, the redistribution of water and soil materials caused by microtopography is the main factor affecting the spatial heterogeneity of soil and the utilization of land resources.

Grazing decreased soil organic carbon by decreasing aboveground biomass in a desert steppe in Inner Mongolia.

The mechanisms through which stocking rates affect soil organic carbon in desert steppe landscapes are not fully understood. To address this research gap, we investigated changes in the biomass of Stipa breviflora plant communities and soils in a desert steppe. Through our research findings, we can establish an appropriate stocking rate for Stipa breviflora desert steppe.

Water causes divergent responses of specific carbon sink to long-term grazing in a desert grassland.

Heavy grazing generally reduces grassland biomass, further decreasing its carbon sink. Grassland carbon sink is determined by both plant biomass and carbon sink per unit biomass (specific carbon sink). This specific carbon sink could reflect grassland adaptative response, because plants generally tend to adaptively enhance the functioning of their remaining biomass after grazing (i.

Changes in the profile properties and chemical weathering characteristics of cultivated soils affected by anthropic activities.

The study of the pedogenic process in response to natural evolution, gradual anthropogenic shifts and engineering upheavals is of great significance for understanding, utilizing and transforming nature in the future. Although scholars have considered anthropic activities to be an important factor affecting pedogenesis, research on how and how much anthropic activities influence the soil-forming process is scant. This paper was conducted to analyse pedogenic characteristics dominated by anthropic activities.

The Impact of Interphase Precipitation on the Mechanical Behavior of Fire-Resistant Steels at an Elevated Temperature.

In this study, we address the challenge of obtaining high strength at ambient and elevated temperatures in fire-resistant Ti-Mo-V steel with ferrite microstructures through thermo-mechanical controlled processing (TMCP). Thermally stable interphase precipitation of (Ti, Mo, V)C was an important criterion for retaining strength at elevated temperatures. Electron microscopy indicated that interphase precipitation occurred during continuous cooling after controlled rolling, where the volume fraction of interphase precipitation was controlled by the laminar cooling temperature.

Mechanized and Optimized Configuration Pattern of Crop-Mulberry Systems for Controlling Agricultural, Non-Point Source Pollution on Sloping Farmland in the Three Gorges Reservoir Area, China.

High-intensity utilization of sloping farmland causes serious soil erosion and agricultural, non-point source pollution (AGNSP) in the Three Gorges Reservoir Area (TGRA). Crop-mulberry systems are important agroforestry systems for controlling soil, water, and nutrient losses. However, there are many different mulberry hedgerow planting patterns in the TGRA.

Determining the Shear Strength and Permeability of Soils for Engineering of New Paddy Field Construction in a Hilly Mountainous Region of Southwestern China.

As a constructed wetland ecosystem, paddy field plays an irreplaceable role in flood storage and detention, groundwater replenishment, environmental protection, and ecological balance maintenance. New paddy field construction can give full play to the production and ecological functions of paddy field and can adjust the development structure of the agricultural industry effectively. The soil properties of shear strength and permeability, which provide a theoretical basis for engineering design, construction, and post-operation, are important indexes in the site selection of new paddy field.

Typical steppe ecosystems maintain high stability by decreasing the connections among recovery, resistance, and variability under high grazing pressure.

Grasslands in Inner Mongolia have been confronted with unprecedented degradation in recent years. Research on ecosystem stability is important to inform evaluation of the health of degraded grassland ecosystems. We examined synthetic stability, which was defined by the relationships between multiple components of stability, known as multidimensional stability, in grasslands at four stages of degradation (undegraded, slightly degraded, moderately degraded, and intensely degraded) in the Xilin River Basin, Inner Mongolia, China.

[Effects of Cyclical Temperature Fluctuations on Organic Carbon Mineralization in Purple Soil].

In the natural state, the soil temperature changes periodically throughout the day, but there is no unified opinion on whether the daily variation of soil temperature affects the mineralization of soil organic carbon. Therefore, the effect of cyclical temperature fluctuations on organic carbon mineralization of purple soil, widely distributed in southwest China, was studied by an incubation experiment in the laboratory. These soils were incubated at three constant temperatures (15, 20, and 25℃) with cyclically fluctuating temperatures (the range was within 15/25℃) and two moisture levels (70% water holding capacity (WHC) and submerged condition).

Sensitive voltammetric determination of chloramphenicol by using single-wall carbon nanotube-gold nanoparticle-ionic liquid composite film modified glassy carbon electrodes.

A novel composite film modified glassy carbon electrode has been fabricated and characterized by scanning electron microscope (SEM) and voltammetry. The composite film comprises of single-wall carbon nanotube (SWNT), gold nanoparticle (GNP) and ionic liquid (i.e.

Direct electrochemistry of glucose oxidase entrapped in nano gold particles-ionic liquid-N,N-dimethylformamide composite film on glassy carbon electrode and glucose sensing.

The direct electrochemistry of glucose oxidase (GOD) entrapped in nano gold particles (NAs)-N,N-dimethylformamide (DMF)-1-butyl-3-methylimidazolium hexafluophosphate (BMIMPF(6)) composite film on a glassy carbon electrode (NAs-DMF-GOD (BMIMPF(6))/GC) has been investigated for first time. The immobilized GOD exhibits a pair of well-defined reversible peaks in 0.050 M pH 5 phosphate solutions (PS), resulting from the redox of flavin adenine dinucleotide (FAD) in GOD.