Stochastic temporal and spatiotemporal models of metastable pitting on a metal surface are presented. A stochastic reaction-diffusion model accounts for the effects of local changes in concentration, potential drop, and oxide film damage on the nucleation of subsequent events. The cooperative interactions among events can lead to the formation of clusters of metastable pits and to an explosive growth in the total number of pits.
View Article and Find Full Text PDFPhys Chem Chem Phys
June 2006
Experiments are carried out with a chemical burster, the electrodissolution of iron in sulfuric acid solution. The system exhibits bursting oscillations in which fast periodic spiking is superimposed on chaotic, slow oscillations. Regularization of the slow dynamics, i.
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