This study focused on developing and evaluating a continuous flow photoreactor with an immobilized photocatalyst. The titanium dioxide powder was deposited on glass beads and packed into sequentially connected columns surrounded by LED lamps. The volume of the reactor without beads is 2.
View Article and Find Full Text PDFSynthesis of zinc oxide (ZnO) nanoparticles (NPs) was mediated by plant extracts to assist in the reduction of zinc atoms during the synthesis and act as a capping agent during annealing. The preparation used ethanolic extracts from the roots of Japanese knotweed (). Two major outcomes could be made.
View Article and Find Full Text PDFThe application of TiO2 photocatalysis in various environmental fields has been extensively studied in the last decades due to its ability to induce the degradation of adsorbed organic pollutants. In the present work, TiO2 powders doped and co-doped with sulfur and nitrogen and modified with platinum were prepared by particulate sol-gel synthesis. PXRD measurements revealed that the replacement of HCl with H2SO4 during synthesis reduced the size of the crystallites from ~ 30 nm to ~20 nm, increasing the surface area from ~44 m2/g to ~80 m2/g.
View Article and Find Full Text PDFTitanium dioxide photocatalysts have received a lot of attention during the past decades due to their ability to degrade various organic pollutants to CO and HO, which makes them suitable for use in environmental related fields such as air and water treatment and self-cleaning surfaces. In this work, titania thin films and powders were prepared by a particulate sol-gel route, using titanium tetrachloride (TiCl) as a precursor. Afterwards, the prepared sols were doped with nitrogen (ammonium nitrate, urea), sulfur (thiourea) and platinum (chloroplatinic acid), coated onto glass substrates by dip-coating, and thermally treated in a muffle furnace to promote crystallization.
View Article and Find Full Text PDFEnviron Sci Pollut Res Int
July 2018
A compact reactor for photocatalytic oxidation and photocatalytic ozonation water treatment was developed and evaluated by using four model pollutants. Additionally, combinations of pollutants were evaluated. Specially produced AlO porous reticulated monolith foams served as TiO carriers, offering a high surface area support.
View Article and Find Full Text PDFDoped (Au, Ag) and undoped TiO2 thin films were prepared on soda-lime glass via the sol-gel method by dip-coating from TiCl4 precursor, followed by 30 minutes calcination at 500 °C to obtain transparent thin films with good adhesion to the substrate. XRD analysis showed that the particle size of samples heat treated at 500 °C was ~10 nm for all of the samples prepared, both doped and undoped ones. SEM images revealed that the thin film surface was homogeneous and nano-porous.
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