Evaporation has been one of the most classic desalination processes on the Earth. When we try to use the power of water flow itself, the evaporation process can perform even better. Here, we report a hydrodynamic solar-driven interfacial evaporation process which water evaporation rate can achieve 6.
View Article and Find Full Text PDFRecent advances in solar-driven interfacial evaporation (SDIE) have led to high evaporation rates that open promising avenues for practical utilization in freshwater production and industrial application for pollutant and nutrient concentration, and resource recovery. Breakthroughs in overcoming the theoretical limitation of 2D interfacial evaporation have allowed for developing systems with high evaporation rates. This study presents a comprehensive review of various evaporator designs that have achieved pure evaporation rates beyond 4 kg m h, including structural and material designs allowing for rapid evaporation, passive 3D designs, and systems coupled with alternative energy sources of wind and joule heating.
View Article and Find Full Text PDFMembrane distillation (MD) shows promise for achieving high salinity treatment and zero liquid discharge (ZLD) compared to conventional water treatment processes due to its unique characteristics, including low energy consumption and high resulting water quality. However, performance degradation due to fouling and scaling under high recovery conditions remains a challenge, particularly considering the need to control both cations and anions for maximum scaling mitigation. Accordingly, in this study, alternating current (AC) operation for electrically conductive membrane distillation (ECMD) is newly proposed, based on its potential for controlling both cations and anions, in contrast to conventional direct current (DC) operation.
View Article and Find Full Text PDFThermally localized solar-driven water evaporation (SWE) in recent years has increasingly been developed due to the potential of cost-efficient freshwater production from small-scale portable devices. In particular, the multistage SWE has attracted much attention as the systems possess mostly a simple foundational structure and high solar-to-thermal conversion output rates, enough to produce freshwater from 1.5 L mh (LMH) to 6 LMH.
View Article and Find Full Text PDFIn this work, inkjet printing technology was used to print a thin layer of a hydrophilic solution containing polydopamine as a binder and polyethyleneimine as a strong hydrophilic agent on a commercial hydrophobic membrane to produce a Janus membrane for membrane distillation. The pristine and modified membranes were tested in a direct-contact membrane distillation system with mineral oil-containing feedwater. The results revealed that an integrated and homogenous hydrophilic layer was printed on the membrane with small intrusions in the pores.
View Article and Find Full Text PDFIn this study, a composite electrospun nanofiber membrane was fabricated and used to treat a geothermal brine source with lithium enrichment. An in-situ growth technique was applied to incorporate silica nanoparticles on the surface of nanofibers with (3-Aminopropyl) triethoxysilane as the nucleation site. The fabricated composite nanofiber membrane was heat pressed to enhance the integration of the membrane and its mechanical stability.
View Article and Find Full Text PDFAzithromycin (AZIM) is considered as one of the most frequently prescribed antibiotics (ABs) in the world by medical professionals. This study explored, two novel, cheap and environmentally beneficial adsorbents i.e.
View Article and Find Full Text PDFIn this study, a comprehensive model was developed using Computational Fluid Dynamics (CFD), and the behaviour of a direct contact membrane distillation (DCMD) system was investigated at hypersaline feedwater conditions. The effects of various operating parameters including feed and permeate velocities, temperatures and salinities, as well as different membrane characteristics like thickness, porosity, and thermal conductivity were studied. The developed simulation model was also validated using experimental data.
View Article and Find Full Text PDFInterfacial solar water evaporation has attracted tremendous attention for sunlight harvesting for water purification. However, salt formation and stability of the photothermal materials (PTMs) remain a challenge that need addressing before bringing this technology to real-world applications. In this work, a nanoscale thin film of gold (Au) on a polytetrafluoroethylene (PTFE) membrane has been prepared using a magnetic sputtering technique.
View Article and Find Full Text PDFThe feasibility of preparing TiO/g-CN heterojunction from Ti-incorporated dried dye wastewater sludge is explored in this study. Two reaction routes of composite formation were evaluated. In the initial approach, one-step calcination of dried sludge and melamine mixture @600 °C was carried out.
View Article and Find Full Text PDFIn this study, a 1000 L/d capacity one-off on-site wastewater treatment system was operated for over a year as a pilot alternative to the conventional on-site treatment as currently used in urban Bhutan. An up-flow anaerobic sludge blanket (UASB) was used for blackwater treatment (to replace "septic tank followed by an anaerobic biofilter (ABF) (to replace soak pits) for the treatment of a mixture of greywater and UASB effluent. Shredded waste plastic bottles were used as the novel biofilter media in the ABF.
View Article and Find Full Text PDFIn this study, sludges generated from Ti-based flocculation of dye wastewater were used to retrieve photoactive titania (S-TiO). It was heterojunctioned with graphitic carbon nitride (g-CN) to augment photoactivity under UV/visible light irradiance. Later the as-prepared samples were utilized to remove nitrogen oxides (NO) in the atmospheric condition through photocatalysis.
View Article and Find Full Text PDFAdv Colloid Interface Sci
March 2021
Membrane distillation (MD) is a promising hybrid thermal-membrane separation technology that can efficiently produce freshwater from seawater or contaminated wastewater. However, the relatively low flux and the presence of fouling or wetting agents in feed solution negate the applicability of MD for long term operation. In recent years, 'two-faced' membranes or Janus membranes have shown promising potential to decrease wetting and fouling problem of common MD system as well as enhance the flux performance.
View Article and Find Full Text PDFFor the purpose of atmospheric NO removal, anatase TiO/g-CN photocatalytic composites were prepared by using a facile template-free calcination route in atmospheric conditions. Considerably fiscal NP400 and laboratory-grade melamine were used as the precursor of the composites. Additionally, samples were prepared with different wt.
View Article and Find Full Text PDFNanofibers are one of the most attractive materials in various applications due to their unique properties and promising characteristics for the next generation of materials in the fields of energy, environment, and health. Among the many fabrication methods, electrospinning is one of the most efficient technologies which has brought about remarkable progress in the fabrication of nanofibers with high surface area, high aspect ratio, and porosity features. However, neat nanofibers generally have low mechanical strength, thermal instability, and limited functionalities.
View Article and Find Full Text PDFThis study focused on the preparation of undoped and Ca-doped titania from flocculation generated sludge. Initially, TiCl was utilised to perform coagulation and flocculation in synthetic wastewater and an optimised dose of coagulant was determined by evaluating the turbidity, dissolved organic carbon (DOC) and zeta potential of the treated water. Later, using Ca(OH) as a coagulant aid, the effects on effluent pH, turbidity and DOC removal were investigated.
View Article and Find Full Text PDFNanoscale zero-valent iron (nZVI), with its high reactivity towards a broad range of contaminants, has been a promising material for groundwater remediation. Membrane-supported nZVI can both avoid nZVI agglomeration for better reactivity and recycle nZVI to lower the risk of secondary pollution. In this study, we successfully fabricated a PVDF-GO membrane via electrospinning technology and employed the functionalized nanofiber membrane to immobilize nZVI particles.
View Article and Find Full Text PDFThis study aimed at improving membrane distillation (MD) performance by mixing various non-solvents (NSs) in polymer dope solutions. The effect of each NS on the inner structure and surface morphology of hollow fiber (HF) membrane was investigated. Membrane morphology is manipulated by controlling liquid-liquid (L-L) and solid-liquid (S-L) demixing time, which is a function of the viscosity and water affinity of dope solutions.
View Article and Find Full Text PDFThe effects of bioreactor temperatures and salinities of an anaerobic membrane distillation bioreactor (anMDBR) on the permeation performance and their potential recovery of bioresources were fully examined in this study. To the best of our knowledge, this is the first study of a lab-scale anMDBR process utilizing sub-merged hollow fiber membranes. The hybrid system utilizing both membrane distillation (MD) and anaerobic bioreactors achieved 99.
View Article and Find Full Text PDFElectrospun nanofiber-supported thin film composite membranes are among the most promising membranes for seawater desalination via forward osmosis. In this study, a high-performance electrospun polyvinylidenefluoride (PVDF) nanofiber-supported thin film composite (TFC) membrane was successfully fabricated after molecular layer-by-layer polyelectrolyte deposition. Negatively-charged electrospun polyacrylic acid (PAA) nanofibers were deposited on electrospun PVDF nanofibers to form a support layer consisted of PVDF and PAA nanofibers.
View Article and Find Full Text PDFIn this study, composite membranes were fabricated via layer-by-layer (LBL) assembly of negatively charged silica aerogel (SiA) and 1H,1H,2H,2H-perfluorodecyltriethoxysilane (FTCS) on a polyvinylidene fluoride phase inversion membrane and interconnecting them with positively charged poly(diallyldimethylammonium chloride) (PDDA) via electrostatic interaction. The results showed that the PDDA-SiA-FTCS coated membrane had significantly enhanced the membrane structure and properties. New trifluoromethyl and tetrafluoroethylene bonds appeared at the surface of the coated membrane, which led to lower surface free energy of the composite membrane.
View Article and Find Full Text PDFSolar photocatalytic degradation of organic water pollutants can be used to degrade toxic organic pollutants in water. In this study, potassium titanate nanofibres were synthesized by an aqueous peroxide route at high pH and examined as photocatalysts for photodegradation of methylene blue (MB) using a solar simulator. Initially, MB was adsorbed on the surface of potassium polytitanates to achieve adsorption equilibrium before the photocatalysts were illuminated using solar simulator.
View Article and Find Full Text PDFThe aim of this study was to determine the effect of powdered activated carbon (PAC) on the overall performance of a submerged membrane bioreactor (SMBR) system integrated with nanofiltration (NF) for wastewater reclamation. It was found that the trans-membrane pressure of SMBR increased continuously while that of the SMBR with PAC was more stable, mainly because water could still pass through the PACs and membrane even though foulants adhered on the PAC surface. The presence of PAC was able to mitigate fouling in SMBR as well as in NF.
View Article and Find Full Text PDFIn the past few years, silica-modified titania has drawn increasing attention due to their special properties making them ideal candidates for a wide range of applications. In this study, we report a novel method for the synthesis of silica-modified titania by a sol-gel method using sodium silicate solution (1 M). The hydrolysis and condensation reactions of titanium dioxide (TiO2, Degussa Aeroxide® P25) in sodium silicate solution proceeded with citric acid (3 M) as a catalyst.
View Article and Find Full Text PDFIn this paper, we investigated the effect of laser polishing at different treatment times on the surface roughness and corrosion resistance of a biliary nickel-titanium (NiTi or Nitinol) stent. A specific area of the stent wire surface was checked for changes in roughness by scanning electron microscopy (SEM) and a noncontact profilometer. The corrosion resistance was assessed by potentiodynamic polarization test and electrochemical impedance spectroscopy.
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