Enhanced Predictability of Urea Crystallization by an Optimized Laser Repetition Rate.

Laser-induced crystallization is a novel alternative to classical methods for crystallizing organic molecules but requires a judicious choice of experimental parameters for the onset of crystallization to be predictable. This study investigated the impact of the laser repetition rate on the time delay from the start of the pulsed laser illumination to the initiation of crystallization, the so-called induction time. A supersaturated urea solution was irradiated with near-infrared (λ = 1030 nm) laser pulses of pulse duration τ = 5 ps at a pulse energy of approximately = 340 μJ while varying the repetition rate from 10 to 20,000 Hz.

Simulating multilevel diffractive optical elements on a spatial light modulator.

Multilevel diffractive optical elements (DOEs) offer a solution to approximate complex diffractive phase profiles in a stepwise manner. However, while much attention has focused on efficiency, the impact on modal content in the context of structured light has, to our best knowledge, remained unexplored. Here, we outline a simple theory that accounts for efficiency and modal purity in arbitrary structured light produced by multilevel DOEs.