Organic ionic plastic crystals having colossal barocaloric effects for sustainable refrigeration.

Barocaloric (BC) materials offer the potential for highly energy-efficient refrigeration by generating heat absorption through the effect of pressure on a solid-solid phase transition. However, very few of the known materials have the required phase transition in the temperature regions necessary for domestic refrigeration or air conditioning. We introduce organic ionic plastic crystals (OIPCs) as a new family of BC materials.

Capture, Storage, and Release of Oxygen by Metal-Organic Frameworks (MOFs).

Oxygen is a critical gas for medical and industrial settings. Much of today's global oxygen supply is via inefficient technologies such as cryogenic distillation, membranes or zeolites. Metal-organic frameworks (MOFs) promise a superior alternative for oxygen separation, as their fundamental chemistry can in principle be tailored for reversible and selective oxygen capture.

Performance evaluation of CuBTC composites for room temperature oxygen storage.

Oxygen is commonly separated from air using cryogenic liquefaction. The inherent energy penalties of phase change inspire the search for energy-efficient separation processes. Here, an alternative approach is presented, where we determine whether it is possible to utilise simpler, stable materials in the right process to achieve overall energy efficiency.