Hierarchical *BEA-type nanosponges zeolite with a high external surface area (116 m.g) and small crystal size, synthesized in the presence of a dual-porogenic organic compound, were modified with a cationic surfactant (HDTMABr: hexadecyltrimethyl ammonium bromide) in order to create a new anion exchanger system: the surfactant-modified zeolite nanosponges (SMZ). For comparison, two other surfactant-modified *BEA-type zeolite materials, SMZ and SMZ, were obtained by modifying the synthesized conventional micron-size microcrytals and nanocrystals *BEA-type zeolite with HDTMABr, respectively.
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