Publications by authors named "Lawrence Cathles"

The existence of a thin, weak asthenospheric layer beneath Earth's lithospheric plates is consistent with existing geological and geophysical constraints, including Pleistocene glacio-isostatic adjustment, modeling of gravity anomalies, studies of seismic anisotropy, and post-seismic rebound. Mantle convection models suggest that a pronounced weak zone beneath the upper thermal boundary layer (lithosphere) may be essential to the plate tectonic style of convection found on Earth. The asthenosphere is likely related to partial melting and the presence of water in the sub-lithospheric mantle, further implying that the long-term evolution of the Earth may be controlled by thermal regulation and volatile recycling that maintain a geotherm that approaches the wet mantle solidus at asthenospheric depths.

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Understanding nanoparticle-surface adhesion is necessary to develop inert tracers for subsurface applications. Here we show that nanoparticles with neutral surface charge may make the best subsurface tracers, and that it may be possible to used SiO2 nanoparticle retention to measure the fraction of solid surface that has positive charge. We show that silica nanoparticles dispersed in NaCl electrolyte solutions are increasingly retained in calcium carbonate (calcite) sand-packed columns as the solution ionic strength increases, but are not retained if they are injected in pure water or Na2SO4 electrolyte solutions.

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Knowledge of micrometer-size polyacrylamide elastic microsphere (MPEM) transport and retention mechanisms in porous media is essential for the application of MPEMs as a smart sweep improvement and profile modification agent in improving oil recovery. A transparent micromodel packed with translucent quartz sand was constructed and used to investigate the pore-scale transport, surface deposition-release, and plugging deposition-remigration mechanisms of MPEMs in porous media. The results indicate that the combination of colloidal and hydrodynamic forces controls the deposition and release of MPEMs on pore-surfaces; the reduction of fluid salinity and the increase of Darcy velocity are beneficial to the MPEM release from pore-surfaces; the hydrodynamic forces also influence the remigration of MPEMs in pore-throats.

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