Dynamic NMR Relaxometry as a Straightforward Measurement of Concentration Variations in Colloidal Gels.

We show that dynamic NMR relaxometry allows one to probe the particle size or the concentration evolution over time in homogeneous colloidal suspensions or the concentration in different regions of heterogeneous suspensions, up to large volume fractions. We first demonstrate that the NMR transverse relaxation time is independent of the gel structure at the particle scale so that it only slightly varies during the gelation of a colloidal suspension. The evolution over time of the NMR transverse relaxation time during gel drying and its analysis with the help of the fast-exchange assumption extended to a partially saturated medium then allowed us to identify three successive regimes: homogeneous shrinkage, desaturation, and molecular film regime.

Viscous friction of squeezed bubbly liquid layers.

Shear viscosity of bubbly liquids is known to depend on both the gas volume fraction and the capillary number. Here, we study the impact of confinement on their behavior by investigating the viscosity of semi-dilute bubbly liquid layers confined between two plates and characterized by a ratio of the undeformed bubble diameter to the layer thickness equal to or larger than unity. For all the studied confinement ratios, viscosity is shown to be smaller than the viscosity of the suspending liquid for capillary numbers larger than 0.

MRI investigation of granular interface rheology using a new cylinder shear apparatus.

The rheology of granular materials near an interface is investigated through proton magnetic resonance imaging. A new cylinder shear apparatus has been inserted in the magnetic resonance imaging device, which allows the control of the radial confining pressure exerted by the outer wall on the grains and the measurement of the torque on the inner shearing cylinder. A multi-layer velocimetry sequence has been developed for the simultaneous measurement of velocity profiles in different sample zones, while the measurement of the solid fraction profile is based on static imaging of the sample.