Influence of redox initiator component ratios on the emulsion copolymerisation of vinyl acetate and neodecanoic acid vinyl ester.

Redox initiated emulsion polymerisation of vinyl acetate and neodecanoic acid vinyl ester was investigated at temperatures ranging from -1 °C to 87 °C (initiation temperature between -1 °C and 60 °C), using varying molar ratios of the following redox components: l-ascorbic acid, -butyl hydroperoxide and ammonium iron(iii) sulfate dodecahydrate as a catalyst. The high flexibility of redox initiators enables product properties, as well as space-time-yield, to be adjusted as required. Polymers being products by process, it was presumed that modifying the conversion rate would lead to a different product.

Scale-up of Emulsion Polymerisation up to 100 L and with a Polymer Content of up to 67 wt%, Monitored by Photon Density Wave Spectroscopy.

The scale-up process of the high solid content (up to 67 wt%) emulsion polymerisation of vinyl acetate and Versa10 from 1 L over 10 L to 100 L was investigated. An emulsion copolymerisation of vinyl acetate and neodecanoic acid vinyl ester in a molar ratio of 9:1 was carried out in a starved-fed semi-batch operation. As a radical source, a redox initiator system consisting of L-ascorbic acid, tert-butyl hydroperoxide and ammonium iron (III) sulphate was used.

In-line monitoring of latex-particle size during emulsion polymerizations with a high polymer content of more than 60.

The photon density wave (PDW) spectroscopy is established in the fields of biochemistry and food chemistry as an online analytical method for the determination of mean particle sizes. This work examines PDW spectroscopy regarding its potential in high solid content emulsion polymerization. For this reason, emulsion copolymerization with a tendency for agglomeration of vinyl acetate and Versa® 10 in a molar ratio of 9 : 1, and with varying emulsifier content, was carried out in semi-batch operation mode with different target particle sizes from 50 to 325 nm.