High Voltage: The Molecular Properties of Redox-Active Dissolved Organic Matter in Northern High-Latitude Lakes.

Redox-active functional groups in dissolved organic matter (DOM) are crucial for microbial electron transfer and methane emissions. However, the extent of aquatic DOM redox properties across northern high-latitude lakes and their relationships with DOM composition have not been thoroughly described. We quantified electron donating capacity (EDC) and electron accepting capacity (EAC) in lake DOM from Canada to Alaska and assessed their relationships with parameters from absorbance, fluorescence, and ultrahigh resolution mass spectrometry (FT-ICR MS) analyses.

Development of Ice-Shelf Estuaries Promotes Fractures and Calving.

As the global climate warms, increased surface meltwater production on ice shelves may trigger ice-shelf collapse and enhance global sea-level rise. The formation of surface rivers could help prevent ice-shelf collapse if they can efficiently evacuate meltwater. Here, we present observations of the evolution of a surface river into an ice-shelf estuary atop the Petermann Ice Shelf in northwest Greenland, and identify a second estuary at the nearby Ryder Ice Shelf.

Human alteration of global surface water storage variability.

Knowing the extent of human influence on the global hydrological cycle is essential for the sustainability of freshwater resources on Earth. However, a lack of water level observations for the world's ponds, lakes and reservoirs has limited the quantification of human-managed (reservoir) changes in surface water storage compared to its natural variability. The global storage variability in surface water bodies and the extent to which it is altered by humans therefore remain unknown.

Dark zone of the Greenland Ice Sheet controlled by distributed biologically-active impurities.

Albedo-a primary control on surface melt-varies considerably across the Greenland Ice Sheet yet the specific surface types that comprise its dark zone remain unquantified. Here we use UAV imagery to attribute seven distinct surface types to observed albedo along a 25 km transect dissecting the western, ablating sector of the ice sheet. Our results demonstrate that distributed surface impurities-an admixture of dust, black carbon and pigmented algae-explain 73% of the observed spatial variability in albedo and are responsible for the dark zone itself.

Direct measurements of meltwater runoff on the Greenland ice sheet surface.

Meltwater runoff from the Greenland ice sheet surface influences surface mass balance (SMB), ice dynamics, and global sea level rise, but is estimated with climate models and thus difficult to validate. We present a way to measure ice surface runoff directly, from hourly in situ supraglacial river discharge measurements and simultaneous high-resolution satellite/drone remote sensing of upstream fluvial catchment area. A first 72-h trial for a 63.

Efficient meltwater drainage through supraglacial streams and rivers on the southwest Greenland ice sheet.

Thermally incised meltwater channels that flow each summer across melt-prone surfaces of the Greenland ice sheet have received little direct study. We use high-resolution WorldView-1/2 satellite mapping and in situ measurements to characterize supraglacial water storage, drainage pattern, and discharge across 6,812 km(2) of southwest Greenland in July 2012, after a record melt event. Efficient surface drainage was routed through 523 high-order stream/river channel networks, all of which terminated in moulins before reaching the ice edge.

Toward global mapping of river discharge using satellite images and at-many-stations hydraulic geometry.

Rivers provide critical water supply for many human societies and ecosystems, yet global knowledge of their flow rates is poor. We show that useful estimates of absolute river discharge (in cubic meters per second) may be derived solely from satellite images, with no ground-based or a priori information whatsoever. The approach works owing to discovery of a characteristic scaling law uniquely fundamental to natural rivers, here termed a river's at-many-stations hydraulic geometry.

New Trans-Arctic shipping routes navigable by midcentury.

Recent historic observed lows in Arctic sea ice extent, together with climate model projections of additional ice reductions in the future, have fueled speculations of potential new trans-Arctic shipping routes linking the Atlantic and Pacific Oceans. However, numerical studies of how projected geophysical changes in sea ice will realistically impact ship navigation are lacking. To address this deficiency, we analyze seven climate model projections of sea ice properties, assuming two different climate change scenarios [representative concentration pathways (RCPs) 4.

Methane bubbling from northern lakes: present and future contributions to the global methane budget.

Large uncertainties in the budget of atmospheric methane (CH4) limit the accuracy of climate change projections. Here we describe and quantify an important source of CH4 -- point-source ebullition (bubbling) from northern lakes -- that has not been incorporated in previous regional or global methane budgets. Employing a method recently introduced to measure ebullition more accurately by taking into account its spatial patchiness in lakes, we estimate point-source ebullition for 16 lakes in Alaska and Siberia that represent several common northern lake types: glacial, alluvial floodplain, peatland and thermokarst (thaw) lakes.

Rapid early development of circumarctic peatlands and atmospheric CH4 and CO2 variations.

An analysis of 1516 radiocarbon dates demonstrates that the development of the current circumarctic peatlands began approximately 16.5 thousand years ago (ka) and expanded explosively between 12 and 8 ka in concert with high summer insolation and increasing temperatures. Their rapid development contributed to the sustained peak in CH4 and modest decline of CO2 during the early Holocene and likely contributed to CH4 and CO2 fluctuations during earlier interglacial and interstadial transitions.