Characterization of the sorption of gaseous and organic solutes onto polydimethyl siloxane solid-phase microextraction surfaces using the Abraham model.

Water-to-polydimethylsiloxane (PDMS) and gas-to-PDMS sorption coefficients have been compiled for 170 gaseous and organic solutes. Both sets of sorption coefficients were analyzed using the Abraham solvation parameter model. Correlations were obtained for both "dry" headspace solid-phase microextraction and conventional "wet" PDMS coated surfaces.

Comment on "systematic investigation of the sorption properties of polyurethane foams for organic vapors".

A method was devised for combining experimental partition coefficients measured at different temperatures into a single regression correlation. The proposed method described the 265 experimental air-to-polyurethane ether adsorption coefficients reported by Kamprad and Goss (Kamprad, I.; Goss, K.

Linear free energy relationship correlation of the distribution of solutes between water and sodium dodecyl sulfate (SDS) micelles and between gas and SDS micelles.

Data have been assembled from the published literature on the water-to-micellar sodium dodecyl sulfate (SDS) partition coefficient data for more than 200 compounds and on the gas-to-micellar SDS partition coefficient data for more than 140 compounds. It is shown that an Abraham solvation equation with only five descriptors can be used to correlate the observed partition coefficient data to within a standard deviation of 0.22 log units.

Characterization of the retention behavior of organic and pharmaceutical drug molecules on an immobilized artificial membrane column with the Abraham model.

Data have been compiled from the published literature on the retention factors of 174 organic compounds and drug molecules eluted from a Regis Technologies IAM.PC.DD2 HPLC column using an aqueous mobile phase buffered in the pH range of pH 6.

Characterization of room-temperature ionic liquids by the Abraham model with cation-specific and anion-specific equation coefficients.

Gas-to-RTIL (room-temperature ionic liquid) partition coefficients have been compiled for 592 different solute-RTIL combinations. These partition coefficients were converted into water-to-RTIL partition coefficients using the corresponding gas-to-water partition coefficients. Both sets of partition coefficients were analyzed using the Abraham solvation parameter model with cation-specific and anion-specific equation coefficients.