Fluorous membrane ion-selective electrodes for perfluorinated surfactants: trace-level detection and in situ monitoring of adsorption.

Ion-selective electrodes (ISEs) with fluorous anion-exchanger membranes for the potentiometric detection of perfluorooctanoate (PFO(-)) and perfluorooctanesulfonate (PFOS(-)) were developed. Use of an anion-exchanger membrane doped with the tetraalkylphosphonium derivative (Rf8(CH2)2)(Rf6(CH2)2)3P(+) and an optimized measurement protocol resulted in detection limits of 2.3 × 10(-9) M (1.