Gigahertz free-space electro-optic modulators based on Mie resonances.

Electro-optic modulators are essential for sensing, metrology and telecommunications. Most target fiber applications. Instead, metasurface-based architectures that modulate free-space light at gigahertz (GHz) speeds can boost flat optics technology by microwave electronics for active optics, diffractive computing or optoelectronic control.

Electro-optic spatial light modulator from an engineered organic layer.

Tailored nanostructures provide at-will control over the properties of light, with applications in imaging and spectroscopy. Active photonics can further open new avenues in remote monitoring, virtual or augmented reality and time-resolved sensing. Nanomaterials with χ nonlinearities achieve highest switching speeds.

Design and synthesis of chromophores with enhanced electro-optic activities in both bulk and plasmonic-organic hybrid devices.

This study demonstrates enhancement of in-device electro-optic activity a series of theory-inspired organic electro-optic (OEO) chromophores based on strong (diarylamino)phenyl electron donating moieties. These chromophores are tuned to minimize trade-offs between molecular hyperpolarizability and optical loss. Hyper-Rayleigh scattering (HRS) measurements demonstrate that these chromophores, herein described as BAH, show >2-fold improvement in standard chromophores such as JRD1, and approach that of the recent BTP and BAY chromophore families.

Broadband Metallic Fiber-to-Chip Couplers and a Low-Complexity Integrated Plasmonic Platform.

We present a plasmonic platform featuring efficient, broadband metallic fiber-to-chip couplers that directly interface plasmonic slot waveguides, such as compact and high-speed electro-optic modulators. The metallic gratings exhibit an experimental fiber-to-slot coupling efficiency of -2.7 dB with -1.

Silicon-organic hybrid (SOH) Mach-Zehnder modulators for 100 GBd PAM4 signaling with sub-1 dB phase-shifter loss.

We report on compact and efficient silicon-organic hybrid (SOH) Mach-Zehnder modulators (MZM) with low phase-shifter insertion loss of 0.7 dB. The 280 µm-long phase shifters feature a -voltage-length product of 0.

100 GBd IM/DD transmission over 14 km SMF in the C-band enabled by a plasmonic SSB MZM.

100 Gb/s NRZ-OOK transmission over 14 km standard single mode fiber in the C-band is demonstrated with a simple intensity modulation and direct detection scheme. The transmission concept utilizes single sideband modulation and comprises a single differential digital-to-analog converter with adjustable phase offset, a new dual electrode plasmonic Mach-Zehnder modulator, a laser at 1537.5 nm, standard single mode fibers, a photodiode, an analog-to-digital converter, and linear offline digital signal processing.

Compact and ultra-efficient broadband plasmonic terahertz field detector.

Terahertz sources and detectors have enabled numerous new applications from medical to communications. Yet, most efficient terahertz detection schemes rely on complex free-space optics and typically require high-power lasers as local oscillators. Here, we demonstrate a fiber-coupled, monolithic plasmonic terahertz field detector on a silicon-photonics platform featuring a detection bandwidth of 2.

Organic Semiconductors at the University of Washington: Advancements in Materials Design and Synthesis and toward Industrial Scale Production.

Research at the University of Washington regarding organic semiconductors is reviewed, covering four major topics: electro-optics, organic light emitting diodes, organic field-effect transistors, and organic solar cells. Underlying principles of materials design are demonstrated along with efforts toward unlocking the full potential of organic semiconductors. Finally, opinions on future research directions are presented, with a focus on commercial competency, environmental sustainability, and scalability of organic-semiconductor-based devices.

120 GBd plasmonic Mach-Zehnder modulator with a novel differential electrode design operated at a peak-to-peak drive voltage of 178 mV.

A new plasmonic Mach-Zehnder modulator is demonstrated at a bit rate of 120 Gb/s NRZ-OOK with low peak-to-peak driving voltages of 178 mV below the HD-FEC limit. Such record low driving voltage requirements potentially translate into an electrical drive power consumption of 862 aJ/bit. The low drive voltages have been made possible by a new differential Mach-Zehnder modulator electrode design.

Molecular Engineering of Structurally Diverse Dendrimers with Large Electro-Optic Activities.

To boost electro-optic (EO) performance, a series of multichromophore dendrimers have been developed based on higher hyperpolarizability (CLD-type) chromophore cores that have been used previously (FTC-type dendrimers). The multichromophore dendrimers were molecularly engineered to have either three arms, two arms, or one arm; long or short linkers; and a fluorinated dendron (FD) or tert-butyldiphenylsilyl (TBDPS) shell. The EO performance obtained by FDSD (poling efficiency = 1.

Plasmonic IQ modulators with attojoule per bit electrical energy consumption.

Coherent optical communications provides the largest data transmission capacity with the highest spectral efficiency and therefore has a remarkable potential to satisfy today's ever-growing bandwidth demands. It relies on so-called in-phase/quadrature (IQ) electro-optic modulators that encode information on both the amplitude and the phase of light. Ideally, such IQ modulators should offer energy-efficient operation and a most compact footprint, which would allow high-density integration and high spatial parallelism.

Low-loss plasmon-assisted electro-optic modulator.

For nearly two decades, researchers in the field of plasmonics -which studies the coupling of electromagnetic waves to the motion of free electrons near the surface of a metal -have sought to realize subwavelength optical devices for information technology, sensing, nonlinear optics, optical nanotweezers and biomedical applications . However, the electron motion generates heat through ohmic losses. Although this heat is desirable for some applications such as photo-thermal therapy, it is a disadvantage in plasmonic devices for sensing and information technology and has led to a widespread view that plasmonics is too lossy to be practical.

Nonlinearities of organic electro-optic materials in nanoscale slots and implications for the optimum modulator design.

The performance of highly nonlinear organic electro-optic (EO) materials incorporated into nanoscale slots is examined. It is shown that EO coefficients as large as 190 pm/V can be obtained in 150 nm wide plasmonic slot waveguides but that the coefficients decrease for narrower slots. Possible mechanism that lead to such a decrease are discussed.

Z/E-Isomerism of 3-[4-(dimethylamino)phenyl]-2-(2,4,6-tribromophenyl)acrylonitrile: crystal structures and secondary intermolecular interactions.

The Z and E isomers of 3-[4-(dimethylamino)phenyl]-2-(2,4,6-tribromophenyl)acrylonitrile, CHBrN, (1), were obtained simultaneously by a Knoevenagel condensation between 4-(dimethylamino)benzaldehyde and 2-(2,4,6-tribromophenyl)acetonitrile, and were investigated by X-ray diffraction and density functional theory (DFT) quantum-chemical calculations. The (Z)-(1) isomer is monoclinic (space group P2/n, Z' = 1), whereas the (E)-(1) isomer is triclinic (space group P-1, Z' = 2). The two crystallographically-independent molecules of (E)-(1) adopt similar geometries.

High-speed plasmonic modulator in a single metal layer.

Plasmonics provides a possible route to overcome both the speed limitations of electronics and the critical dimensions of photonics. We present an all-plasmonic 116-gigabits per second electro-optical modulator in which all the elements-the vertical grating couplers, splitters, polarization rotators, and active section with phase shifters-are included in a single metal layer. The device can be realized on any smooth substrate surface and operates with low energy consumption.

Direct Conversion of Free Space Millimeter Waves to Optical Domain by Plasmonic Modulator Antenna.

A scheme for the direct conversion of millimeter and THz waves to optical signals is introduced. The compact device consists of a plasmonic phase modulator that is seamlessly cointegrated with an antenna. Neither high-speed electronics nor electronic amplification is required to drive the modulator.

Who Am I? Who Do You Think I Am? Stability of Racial/Ethnic Self-Identification among Youth in Foster Care and Concordance with Agency Categorization.

While it has been well documented that racial and ethnic disparities exist for children of color in child welfare, the accuracy of the race and ethnicity information collected by agencies has not been examined, nor has the concordance of this information with youth self-report. This article addresses a major gap in the literature by examining: 1) the racial and ethnic self-identification of youth in foster care, and the rate of agreement with child welfare and school categorizations; 2) the level of concordance between different agencies (school and child welfare); and 3) the stability of racial and ethnic self-identification among youth in foster care over time. Results reveal that almost 1 in 5 youth change their racial identification over a one-year period, high rates of discordance exist between the youth self-report of Native American, Hispanic and multiracial youth and how agencies categorize them, and a greater tendency for the child welfare system to classify a youth as White, as compared to school and youth themselves.

Optimizing calculations of electronic excitations and relative hyperpolarizabilities of electrooptic chromophores.

CONSPECTUS: Organic glasses containing chromophores with large first hyperpolarizabilities (β) are promising for compact, high-bandwidth, and energy-efficient electro-optic devices. Systematic optimization of device performance requires development of materials with high acentric order and enhanced hyperpolarizability at operating wavelengths. One essential component of the design process is the accurate calculation of optical transition frequencies and hyperpolarizability.

Nanoscale phase analysis of molecular cooperativity and thermal transitions in dendritic nonlinear optical glasses.

A broad nanoscopic study of a wide-range of dendritic organic nonlinear optical (NLO) self-assembly molecular glasses reveals an intermediate thermal phase regime responsible for both enhanced electric field poling properties and strong phase stabilization after poling. In this paper, the focus is on dendritic NLO molecular glasses involving quadrupolar, liquid crystal, and hydrogen bonding self-assembly mechanisms that, along with chromophore dipole-dipole interactions, dictate phase stability. Specifically, dendritic face-to-face interactions involving arene-perfluoroarene are contrasted to coumarin-containing liquid crystal mesogen and cinnamic ester hydrogen interactions.

Nano-engineering lattice dimensionality for a soft matter organic functional material.

A high performing electro-optic (EO) chromophore with covalently attached coumarin-based pendant groups exhibits intermolecular correlation of coumarin units through molecular dynamics (MD) simulations. Unique, orthogonal molecular orientations of the chromophore and coumarin units are also evident when investigated optically. Such molecular orientation translates to reduced lattice dimensionality of the bulk C1 soft matter material system, leading to increased acentric order and EO activity.

Solvents level dipole moments.

The dipole moments of highly polar molecules measured in solution are usually smaller than the molecular dipole moments that are calculated with reaction field methods, whereas vacuum values are routinely calculated in good agreement with available vapor phase data. Whether from Onsager's theory (or variations thereof) or from quantum mechanical methods, the calculated molecular dipoles in solution are found to be larger than those measured. The reason, of course, is that experiments measure the net dipole moment of solute together with the polarized (perturbed) solvent "cloud" surrounding it.

Organic electro-optic thin films by simultaneous vacuum deposition and laser-assisted poling.

Organic materials with a high second-order optical nonlinearity have an important application for the next generation of computing, telecommunications, and other industries. Because of a high electro-optic coefficient and low dielectric constant, N-benzyl-2-methyl-4-nitroaniline (BNA) single crystals have been grown and their optical properties have been extensively studied. In this Letter, a poled BNA thin film material was prepared through simultaneous vacuum evaporation and laser-assisted electrical poling.

Electro-optic thin films of organic nonlinear optic molecules aligned through vacuum deposition.

Nonlinear optical molecules can be vacuum deposited into uniform thin films using thermal evaporation. Alignment order can be achieved during thin film deposition by an in-plane electrical field poling using electrodes patterned on the substrate. Electro-optic (EO) coefficients, r33 and r13 are independently measured using Young's interferometry technique.

Nonlinear intermodulation distortion suppression in coherent analog fiber optic link using electro-optic polymeric dual parallel Mach-Zehnder modulator.

A linearized dual parallel Mach-Zehnder modulator (DPMZM) based on electro-optic (EO) polymer was both fabricated, and experimentally used to suppress the third-order intermodulation distortion (IMD3) in a coherent analog fiber optic link. This optical transmitter design was based on a new EO chromophore called B10, which was synthesized for applications dealing with the fiber-optic communication systems. The chromophore was mixed with amorphous polycarbonate (APC) to form the waveguide's core material.