Effect of hydrostatic pressure on the supramolecular assembly of surfactant-cyclodextrin inclusion complexes.

The supramolecular assembly of simple colloids into complex, hierarchical structures arises from a delicate interplay of short-range directional and isotropic long-range forces. These assemblies are highly sensitive to environmental changes, such as temperature variations and the presence of specific molecules, making them promising candidates for nanomachine design. In this study, we investigate the effect of hydrostatic pressure, up to 1800 bar, on the supramolecular assemblies of cyclodextrin/surfactant complexes.

Thermoresponsive behavior of cyclodextrin inclusion complexes with weakly anionic alkyl ethoxy carboxylates.

This study investigates the temperature responsive behavior of inclusion complexes formed by weakly anionic alkyl ethoxy carboxylates and α (αCD) and β-cyclodextrins (βCD). Small-angle neutron scattering (SANS) was performed to probe the structural behaviour at the 1-100 nanometer scale of the hierarchical assemblies at different temperatures. The phase transitions and thermodynamics were systematically monitored as a function of the degree of ionization of the surfactant by differential scanning calorimetry (DSC).

Hierarchical assembly of pH-responsive surfactant-cyclodextrin complexes.

In this work, the inclusion complexes of alkyl ethoxy carboxylates with α-cyclodextrin (αCD) and β-cyclodextrin (βCD) were investigated. The thermodynamics of the complexation process was probed by isothermal titration calorimetry (ITC) and volumetry as a function of the degree of ionization of the surfactant. The complexation process was shown to be an enthalpically driven pH-independent process.

Cyclodextrin/surfactant inclusion complexes: An integrated view of their thermodynamic and structural properties.

Cyclodextrins (CDs) play an important role in self-assembly systems of amphiphiles. The structure of CDs provides distinguished physicochemical properties, including the ability to form host-guest complexes. The complexation affects the properties of guest molecules and can produce supramolecular aggregates with desirable characteristics for fundamental and practical applications.