Development of a method based on dispersive liquid-liquid microextraction followed by partial vaporization of the extract for ultra-preconcentration of some pesticide residues in fruit juices.

A new simple and efficient method has been developed for the ultra-preconcentration of multiclass pesticide residues including penconazole, chlorpyrifos, ametryn, clodinafop-propargyl, diniconazole, oxadiazon, and fenpropathrin from some fruit juice samples based on evaporation of the sedimented organic phase obtained from dispersive liquid-liquid microextraction. The enriched target analytes were analyzed by gas chromatography-flame ionization detection. In the microextraction procedure, a mixture of iso-propanol as a disperser and 1,2-dibromoethane as an extraction solvent is quickly injected into an aqueous phase containing the analytes and centrifuged.