Pure-rotational spectrometry (PRS) is an established method, typically used to study structures and properties of polar gas-phase molecules, including isotopic and isomeric varieties. PRS has also been used as an analytical tool where it is particularly well suited for detecting or monitoring low-molecular-weight species that are found in exhaled breath. PRS is principally notable for its ultra-high spectral resolution which leads to exceptional specificity to identify molecular compounds in complex mixtures.
View Article and Find Full Text PDFContinuous-wave NMR studies of 3He in the presence of 99.3% porosity silica aerogel at 34.0 bars and in a magnetic field of 28.
View Article and Find Full Text PDFPhys Rev Lett
September 2000
New NMR studies of 3He in high-porosity aerogel reveal a phase transition from an A-like to a B-like phase on cooling. The evidence includes frequency shift and magnetic susceptibility data, and similar behavior is found in two quite different aerogel samples. The A-like phase is stable only very near to T(c) but can be supercooled to below 0.
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