This research addresses the study of the combined effect of two abiotic treatments, a thermo-oxidative treatment followed by a photo-oxidative treatment with ultraviolet light, on the physicochemical properties of commercially available low-density polyethylene films with an oxo-degradant additive (OXOLDPE) and without (LDPE). The change in the oxidized film properties was characterized using FTIR, XRD, TGA, GPC, and SEM analytical techniques. The results indicated that the increment in carbonyl index (CI) and crystallinity percentage (X) was higher for those films that received the combined oxidative treatments compared with those that received only one of them, thermo- or photo-oxidative treatment.
View Article and Find Full Text PDFNatural nutshell extract was obtained by mechanical compression. The extract was combined with ethanol and a nonionic surfactant, and it was labeled as EES. The EES inhibitor effect on S135 carbon steel, exposed to a simulated marine-coastal environment (SME), was deduced by mass loss measurement, adsorption isotherm, electrochemical measurements, and surface analysis.
View Article and Find Full Text PDFThe change in the corrosion activities of SS304 and the carbon steel A36 were studied during their exposure for 30 days to hybrid pumice-Portland cement extract (CE), to simulate the concrete-pore environment. The ionic composition and the initial pH (12.99) of the CE were influenced by the reduction of Portland cement (PC) content, volcanic pumice oxides and alkaline activators.
View Article and Find Full Text PDFStainless steel SS430 and carbon steel B450C were exposed for 30 days to the aqueous extract of sodium silicate-modified limestone-Portland cement as an alternative for the partial replacement of the Portland cement clinker. The initial pH of 12.60 was lowered and maintained at an average of 9.
View Article and Find Full Text PDFCarbon steel B450C and low-chromium stainless steel SS430 were exposed for 30 days to supersulfated "SS1" cement extract solution, considered as a "green" alternative for partial replacement of the Portland cement clinker. The initial pH of 12.38 dropped since the first day to 7.
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