: The objective of this paper is to introduce a method to measure the force or pressure over the carpal tunnel indirectly, using a new device to drive the pointer of a computer system. The measurements were compared with those obtained using an ergonomic mouse. Simultaneously, measurements of muscular stress on the digitorum extensor muscle were performed to correlate the applied force against muscle activity.
View Article and Find Full Text PDFBackground: In Italy, egg donation is being allowed again following the ruling by the Constitutional Court N. 162/2014. Nevertheless, the number of voluntary donors is insignificant, probably because no reimbursement is provided.
View Article and Find Full Text PDFThe TEMPO oxoammonium cation has been proven to be both an efficient oxidizing reagent and an electrophilic substrate frequently found in organic reactions. Here, we report that this versatile chemical reagent can also be used as an efficient promoter for C- and N-glycosylation reactions through a Ferrier rearrangement with moderate to high yields. This unprecedented reactivity is explained in terms of a Lewis acid activation of glycal by TEMPO forming a type of glycal-TEMPO mesomeric structure, which occurs through an extended vinylogous hyperconjugation toward the π* orbital [LP → π*, π* → σ*, and LP → π*].
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